Citation: DU Shang-Chao, TAN Hua-Qiao, BI Yan-Feng, YU Yang, LIAO Wu-Ping. Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene：Syntheses, Structures and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 749-756. doi: 10.11862/CJIC.2014.112 shu

Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene：Syntheses, Structures and Magnetic Property

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1 State Key Laboratory of Rare Earth Resource Utilization; Engineering Research Center for the Separation and Purification of REs and Thorium; Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;

Corresponding author: LIAO Wu-Ping,
Received Date: 13 July 2013
Available Online: 20 November 2013
Fund Project: 国家自然科学基金(21221061,51222404,51074148,91026024) (21221061,51222404,51074148,91026024)973项目(2012CBA01206)资助项目。 (2012CBA01206)

Three compounds, [Co₂Th₄(HC8A)₂O₂(OH)₂(DMF)₆](1)、[Ni₂Th₅(H₂C8A)(C8A)O₄(OH)₂(DMF)₅(CH₃OH)₂](2)、[Zn₂Th₆(HC8A)(C8A)O₅(CH₃O)(C₃H₆NO₂)₂(DMF)₅(CH₃OH)](3) (H₈C8A=p-tert-butylcalix[8]arene, DMF=N,N-dimethylformide), were obtained by solvothermal method and characterized by single crystal X-ray diffraction, element analysis, and so on. All these three structures are featured by some sandwich-like units which are constructed by two tail-to-tail calix[8]arene molecules and one in-between 3d-5f polynuclear core. All the calix[8]-arene molecules adopt a double-cone conformation, each cone of calix[8]arene molecule bonds one thorium cation by its lower rim, and two cones of one calixarene molecule is connected by some thorium or transition metal atoms. Magnetic measurement indicates that compound 1 exhibits weak ferromagnetic interaction between the metals at low temperature.
- calixarenes;thorium;3d-5f cluster compounds;crystal structure;magnetic property
1. [1]
  [1] ZHANG Jia-Hua(张家骅), BAO Bo-Rong(包伯荣), XIA Yuan-Xian(夏源贤). Nucl. Technol. (核技术), 1988, 11(10): 27-33
2. [2]
  [2] SHEN Chao-Hong(沈朝洪), BAO Ya-Zhi(包亚之), BAO Bo-Rong(包伯荣), et al. J. Nucl. Radiochem. (核化学与放射化学), 1992, 14(2):94-100
3. [3]
  [3] ZHANG Li-Qing(张丽清), WANG Zhi-Chang(王之昌), WANG Xiao-Huan(王小欢), et al. J. Nucl. Radiochem. (核化学与放射化学), 2006, 28(1):61-64
4. [4]
  [4] Borgne T L, Rivière E, Marrot J, et al. Angew. Chem. Int. Ed., 2000, 39:1647-1649
5. [5]
  [5] Maynard B A, Sykora R E, Maguec J T, et al. Chem. Commun., 2010, 46:4944-4946
6. [6]
  [6] Vaughn A E, Bassil D B, Barnes C L, et al. J. Am. Chem. Soc., 2006, 128:10656-10657
7. [7]
  [7] Mishra A, Abboud K A, Christou G. Inorg. Chem., 2006, 45: 2364-2366
8. [8]
  [8] YAN Bing(闫冰), ZHANG Hong-Jie(张洪杰), NI Jia-Zan (倪嘉缵). Chem. Res. Appl. (化学研究与应用), 1998, 10(2): 111-117
9. [9]
  [9] Harrowfield J, Koutsantonis G. Calixarenes in the Nanoworld. Dordrecht: Springer, 2007:197
10. [10]
  [10] Kajiwara T, Iki N, Yamashita M. Coord. Chem. Rev., 2007, 251:1734-1746
11. [11]
  [11] Bi Y F, Li Y L, Liao W P, et al. Inorg. Chem., 2008, 47: 9733-9735
12. [12]
  [12] Bi Y F, Wang X T, Wang B W, et al. Dalton Trans., 2009, 2250-2254
13. [13]
  [13] Karotsis G, Evangelisti M, Dalgarno S J, et al. Angew. Chem. Int. Ed., 2009, 48:9928-9931
14. [14]
  [14] Karotsis G, Kennedy S, Teat S J, et al. J. Am. Chem. Soc., 2010, 132:12983-12990
15. [15]
  [15] Sanz S, Ferreira K, McIntosh R D, et al. Chem. Commun., 2011, 47:9042-9044
16. [16]
  [16] Xiong K C, Wang X Y, Jiang F L, et al. Chem. Commun., 2012, 48:7456-7458
17. [17]
  [17] Su K Z, Jiang F L, Qian J J, et al. Inorg. Chem., 2013, 52: 3780-3786
18. [18]
  [18] Bergougnant R D, Robin A Y, Fromm K M. Tetrahedron, 2007, 63:10751-10757
19. [19]
  [19] Redshaw C. Coord. Chem. Rev., 2003, 244:45-70
20. [20]
  [20] DU Shang-Chao(杜尚超), BI Yan-Feng(毕研峰), YU Yang (于洋), et al. Sci. Sin.: Chim.(中国科学: 化学), 2012, 42(9): 1356-1363
21. [21]
  [21] Gutsche C D, Dhawan B, No K H, et al. J. Am. Chem. Soc., 1981, 103:3782-3792
22. [22]
  [22] Sheldrick G M. Acta Crystallogr., Sect. A, 2008, 64:112-122
23. [23]
  [23] Spek A L. J. Appl. Crystallogr., 2003, 36:7-13
24. [24]
  [24] Harrowfield J M, Ogden M I, White A H. J. Chem. Soc. Dalton Trans., 1991, 2625-2632
25. [25]
  [25] Brown I D, Altermatt D. Acta Crystallogr., Sect. B, 1985, 41:244-247
26. [26]
  [26] Liu W T, Thorp H H. Inorg. Chem., 1993, 32:4102-4105
27. [27]
  [27] Ugozzoli F, Andreetti G D. J. Inclusion Phenom. Mol. Recognit. Chem., 1992, 13, 337-348
28. [28]
  [28] Yu J Y, Schreiner S, Vaska L. Inorg. Chim. Acta, 1990, 170: 145-147
29. [29]
  [29] Langley S, Helliwell M, Sessoli R, et al. Inorg. Chem., 2008, 47:497-507
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