Citation: DU Shang-Chao, TAN Hua-Qiao, BI Yan-Feng, YU Yang, LIAO Wu-Ping. Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene:Syntheses, Structures and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 749-756. doi: 10.11862/CJIC.2014.112
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Three compounds, [Co2Th4(HC8A)2O2(OH)2(DMF)6](1)、[Ni2Th5(H2C8A)(C8A)O4(OH)2(DMF)5(CH3OH)2](2)、[Zn2Th6(HC8A)(C8A)O5(CH3O)(C3H6NO2)2(DMF)5(CH3OH)](3) (H8C8A=p-tert-butylcalix[8]arene, DMF=N,N-dimethylformide), were obtained by solvothermal method and characterized by single crystal X-ray diffraction, element analysis, and so on. All these three structures are featured by some sandwich-like units which are constructed by two tail-to-tail calix[8]arene molecules and one in-between 3d-5f polynuclear core. All the calix[8]-arene molecules adopt a double-cone conformation, each cone of calix[8]arene molecule bonds one thorium cation by its lower rim, and two cones of one calixarene molecule is connected by some thorium or transition metal atoms. Magnetic measurement indicates that compound 1 exhibits weak ferromagnetic interaction between the metals at low temperature.
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