Citation: ZHANG Jun-Hong, ZHANG Ru-Fen, MA Chun-Lin, WANG Su-Na, WEI Xi-Lian, ZHANG Shao-Liang. Syntheses and Structural Characterization of Triorganotin(Ⅳ) Complexes Containing Pamoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 664-670. doi: 10.11862/CJIC.2014.109
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Three organotin(Ⅳ) complexes {[(Ph3Sn)(pa)]·Et3N}n(1)、 (Bu3Sn)2(pa) (2) and [(Me3Sn)2(pa)]·CH2Cl2(3) were synthesized by the reaction of pamoic acid (H2pa, 2, 3-diphenyl-propionic acid) and the corresponding triorganotin chloride R3SnCl (R=Ph, Bu, Me). All the complexes were characterized by elemental analysis, FTIR, NMR (1H, 13C, 119Sn) spectroscopy and single crystal X-ray diffraction. Structural analyses have revealed that the complex 1 is an infinite polymeric chain, in which each tin atom is linked by the bidentate bridging pamoic acid ligand, the center tin atom adopts a five-coordinated distorted trigonal bipyramidal geometry. However, the complexes 2 and 3 show dinuclear tin structure, the center tin atoms adopt four-coordinated distorted tetrahedral geometry. CCDC: 727157, 1; 892440, 2; 732076, 3.
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