Citation: HU Chun-Yan, NIE Xu-Liang, XIONG Hui, HUANG Chang-Gan. Synthesis, Crystal Structures and Antibacterial Activities of Two Complexes of Copper Assembled by Triazole Pesticides Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 621-626. doi: 10.11862/CJIC.2014.108
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Two copper complexes [CuL41Cl2] (1) and [CuL42Cl2·4H2O] (2) (L1=Uniconazole,L2=Paclobutrazol) were synthesized with triazole pesticides ligands uniconazole and paclobutrazol by solvothermal condition and structurally characterized by element analysis, IR and single crystal X-ray diffraction. Complex 1 is the Triclinic system, space group P1 with a=0.895 6(3) nm, b=1.326 7(4) nm, c=1.491 8(4) nm, α=94.828(3)°, β=97.774(3)°, γ=105.280(3)°, V=1.680 8(9) nm3. Complex 2 is the Triclinic system, space group P1 with a=1.021 89(19) nm, b=1.329(3) nm, c=1.366 4(3) nm, α=81.564(2)°, β=79.508(2)°, γ=79.185(2)°, V=1.785 3(7) nm3. In two complexes, Each six-coordinated Cu(Ⅱ) adopts a distorted octahedral geometry with four nitrogen atoms from triazole ligands and two Cl ions. 1 and 2 was linked into a one dimensional chain by intermolecular hydrogen bonds. Antibacterial activities of complex 1 and 2 increased significantly than corresponding ligands. CCDC: 931901, 1; 932228, 2.
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