Citation: ZHAO Xiu-Hua, ZHAO Ya-Yun, ZHANG Jie, PAN Jian-Guo, LI Xing. Syntheses, Crystal Structures and Fluorescent Spectra of Two Zn(Ⅱ) Complexes with Sulfonamide Pyrimidine[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 633-639. doi: 10.11862/CJIC.2014.107 shu

Syntheses, Crystal Structures and Fluorescent Spectra of Two Zn(Ⅱ) Complexes with Sulfonamide Pyrimidine

1.
1 Faculty of Science, Ningbo University, Ningbo, Zhejiang 315211, China;

Received Date: 7 June 2013
Available Online: 17 November 2013
Fund Project: 中国国家自然科学基金(No.20971075,61078055) (No.20971075,61078055)浙江省自然科学基金(No.LY12B01005) (No.LY12B01005)结构化学国家重点实验室(No.20110010) (No.20110010)

Two new Zn(Ⅱ) compounds, [Zn(L)₂(bpy)] (1) and {[Zn(L)₂(bpp)]}_n (2) (L=sulfonamide pyrimidine, bpy=2,2'-bipyridine, bpp=1,3-bis(4-pyridyl)propane), have been synthesized and characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermal analysis, elemental analysis, IR, UV-Vis and fluorescence. Single crystal X-ray analysis reveals that complex 1 is a mononuclear structure and the Zn(Ⅱ) ion exhibits a tetragonal pyramidal coordination geometry. Complex 2 is a one-dimensional structure and the Zn(Ⅱ) ion is a tetrahedral coordination geometry. Thermal analyses show that complex 1 and 2 have high thermal stability. CCDC: 935049, 1; 935050, 2.
- sulfonamide pyrimidine;Zn(Ⅱ) complex;crystal structure;fluorescence
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