Citation: YANG Shi-Feng, DUAN Hua-Ling, LIN Ji-Jun, ZHU Jian-Ying, GONG Zhen-Bin. A New Method for the Measurement of Complexation Stability Constant and Average Coordination Number of Metallic Element with Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 853-859. doi: 10.11862/CJIC.2014.102
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Anew method using gel filtration chromatography (GFC) and inductively coupled plasma mass spectrometry (ICPMS) was developed for the measurement of complexation stability constant and average coordination number of the complex of metallic ion with polymer. As an example, the binding of PEI with Cu2+ was shown and investigated. The macromolecular PEI-Cu complex and micromolecular species of Cu(Ⅱ) were firstly separated by a low efficiency GFC column with a mobile phase of 0.02 mol·L-1 HAc-NaAc buffer, and then directly introduced into ICPMS for elemental analysis. The results of complexation stability constant and average coordination number characterized by putting the concentration of different species of metallic element into the equations of the novel chemical equilibrium model which was developed in this study. The results shown that the complexation stability constants (KPEI-Cu) were between 109.6 and 1010.7 and the average coordination numbers (n) were in the range of 1.0~1.3 when pHwas changed from 4.1 to 5.3 at 25 ℃. This online, rapid and accurate method of GFC-ICPMS is a novel technique for the research of polymer-metallic complex.
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[1]
[1] Rumeau M, Persin F, Sciers V, et al. J. Membr. Sci., 1992, 73(2/3):313-322
-
[2]
[2] Juang R S, Liang J F. J. Membr. Sci., 1993, 82(1):163-174
-
[3]
[3] Juang R S, Chen M N. Ind. Eng. Chem. Res., 1996, 35(6): 1935-1943
-
[4]
[4] Geckeler K, Lange G, Eberhardt H, et al. Pure Appl. Chem., 1980, 52(7):1883-1905
-
[5]
[5] Rivas B L, Pereira E D, Moreno-Villoslada I. Prog. Polym. Sci., 2003, 28(2):173-208
-
[6]
[6] Geckeler K E, Volchek K. Environ. Sci. Technol., 1996, 30 (3):725-734
-
[7]
[7] Uludag Y, Özbelge H Ö, Yilmaz L. J. Membr. Sci., 1997, 129 (1):93-99
-
[8]
[8] Juang R S, Chiou C H. J. Membr. Sci., 2000, 177(1):207-214
-
[9]
[9] Molinari R, Argurio P, Poerio T. Desalination, 2004, 162: 217-228
-
[10]
[10] Rivas B L, Geckeler K E. Polymer Synthesis Oxidation Processes. Berlin Heidelberg: Springer, 1992:171-188
-
[11]
[11] Cañizares P, Pérez Á, Camarillo R. Desalination, 2002, 144 (1):279-285
-
[12]
[12] Molinari R, Poerio T, Argurio P. J. Membr. Sci., 2007, 295 (1):139-147
-
[13]
[13] LIN Ji-Jun(林继军), DUAN Hua-Ling(段华玲), GONG Zhen-Bin(弓振斌). Chinese J. Anal. Chem.(分析化学), 2011, 39(6):906-910
-
[14]
[14] Kobayashi S, Hiroishi K, Tokunoh M, et al. Macromolecules, 1987, 20(7):1496-1500
-
[15]
[15] Jarvis N V, Wagener J M. Talanta, 1995, 42(2):219-226
-
[16]
[16] LUO Qin-Hui(罗勤慧), SHEN Meng-Chang(沈孟长), DING Yi(丁益), et al. Acta Chim. Sinica(化学学报), 1982, 40(2): 125-133
-
[17]
[17] Çaykara T, İnam R, Öztürk Z, et al. Colloid Polym. Sci., 2004, 282(11):1282-1285
-
[18]
[18] Leyte J C, Zuiderweg L H, Van Reisen M. J. Phys. Chem., 1968, 72(4):1127-1132
-
[19]
[19] Yamaoka K, Masujima T. Bull. Chem. Soc. Jpn., 1979, 52(2): 1286-1296
-
[20]
[20] Tomida T, Hamaguchi K, Tunashima S, et al. Ind. Eng. Chem. Res., 2001, 40(16):3557-3562
-
[21]
[21] Islamoglu Kadioglu S, Yilmaz L, Onder Ozbelge H. Sep. Sci. Technol., 2009, 44(11):2559-2581
-
[22]
[22] HUANG Jia-Hua(黄佳华), GONG Zhen-Bin(弓振斌), LIN Ji-Jun(林继军), et al. Chem. J. Chinese U.(高等学校化学 学报), 2012, 33(12):2633-2637
-
[23]
[23] HUANG Jia-Hua(黄佳华). Thesis for the Master Degree of Xiamen University(厦门大学硕士学位论文). 2012.
-
[24]
[24] Striegel A, Yau W W, Kirkland J J, et al. Modern Size-ex Clusion Liquid Chromatography: Practice of Gel Permeation and Gel Filtration Chromatography. New York: Wiley, 2009.
-
[25]
[25] Yeung B, Marecak D. J. Chromatogr., A, 1999, 852(2):573-581
-
[26]
[26] Rojas E E G, Reis Coimbra dos JS, Minim L A, et al. Process Biochem., 2004, 39(11):1751-1759
-
[27]
[27] Vasudevan P T, Palekar A A, Yan S. Biocatal. Biotransform., 2002, 20(3):189-199
-
[28]
[28] Achterberg E P, Holland T W, Bowie A R, et al. Anal. Chim. Acta, 2001, 442(1):1-14
-
[29]
[29] Liu M, Xie C, Xu W, et al. J. Chromatogr., A, 2004, 1046 (1):121-126
-
[30]
[30] Cutié S S, Martin S J. J. Appl. Polym. Sci., 1995, 55(4):605 -609
-
[31]
[31] ZHANG Han-Qi(张寒琦), TIE Yuan(铁元), WANG Da-Ning (王大宁), et al. Brief Handbook of Analytical Chemistry (分析化学简明教程). Changchun: Jilin University Press, 1996.
-
[32]
[32] Thiele H, Gronau K H. Makromol. Chem., 1963, 59:207-221
-
[33]
[33] Molinari R, Poerio T, Argurio P. Chemosphere, 2008, 70(3): 341-348
-
[34]
[34] Bekturov E A, Bakauova Z K. Synthetic Water-soluble Polymers in Solution. Basel, Heidelberg, New York: Hüthig & Wepf Verlag, 1986.
-
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