Citation: RAN Fan-Min, ZHAO Ya-Yun, ZHAO Xiu-Hua, ZHANG Jie, PAN Jian-Guo, LI Xing. Syntheses, Crystal Structures and Electrochemical Behaviors of Two Co(Ⅱ) Complexes with N-2-Pyrimidinyl-4-amino-benzenesulfonamides[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 913-920. doi: 10.11862/CJIC.2014.092 shu

Syntheses, Crystal Structures and Electrochemical Behaviors of Two Co(Ⅱ) Complexes with N-2-Pyrimidinyl-4-amino-benzenesulfonamides

1.
Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China

Corresponding author: LI Xing,
Received Date: 30 July 2013
Available Online: 26 October 2013
Fund Project: 国家自然科学基金(No.20971075,61078055)；结构化学国家重点实验室基金(No.20110010)；浙江省自然科学基金(No.LY12B01005)；宁波大学王宽诚幸福基金资助项目。 (No.20971075,61078055)；结构化学国家重点实验室基金(No.20110010)；浙江省自然科学基金(No.LY12B01005)

Two new Co(Ⅱ) complexes, [Co(SD)₂(2,2'-bpy)] (1) and {[Co(SD)₂(4,4'-bpy)]·4H₂O}_n (2) (SD=sulfadiazine, 2,2'-bpy=2,2'-bipyridine, 4,4'-bpy=4,4'-bipyridine) have been synthesized through hydrothermal reaction and characterized by elemental analysis, IR, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and cyclic voltammetry (CV). Single crystal X-ray analysis reveals that compound 1 crystallizes in the triclinic system, space group P1 and compound 2 crystallizes in monoclinic crystal system, space group C2/c. It is found that these two compounds have electrochemical response behaviors for H₂O₂ and HCHO.
- sulfadiazine;Co(Ⅱ) complexes;crystal structures;electrochemical behavior
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沈阳化工大学材料科学与工程学院沈阳 110142