Citation: CHENG Xiao-Ning*, ZHANG Wei-Xiong, XUE Wei, CHEN Xiao-Ming*. Syntheses, Structures, and Magnetic Properties of Three Isostructural Coordination Polymers Based on Quinoline-8-oxy-acetate[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 142-148. doi: 10.11862/CJIC.2014.087
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Three isostructural coordination polymers, namely [Ni(8-qoac)Cl]n (1, 8-Hqoac=quinoline-8-oxy-acetic acid), [Fe(8-qoac)Cl]n (2), and [Mn(8-qoac)Cl]n (3) were synthesized under solvothermal reaction conditions. Single-crystal X-ray diffraction studies showed that 1~3 crystallize in the same space group Pbca, in which the octahedral metal ions are first bridged by two chloride ions to form a dinuclear building blocks, and then each dinuclear building block is connected to four adjacent neighbors via four carboxylate groups with the anti-anti coordination mode, giving a two-dimensional layered (4, 4) network considering the dinuclear building blocks as 4-connected nodes and the carboxylate groups as linkers. Magnetic measurements revealed spin-canting-like behaviors for compound 1, while 2 and 3 only exhibit simple antiferromagnetic properties, which can be explained by the different magnetic anisotropic behaviors of the transition metal ions.
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-
[1]
[1] Kurmoo M, Kumagai H, Akita-Tanaka M, et al. Inorg. Chem., 2006, 45:1627-1637
-
[2]
[2] Ruben M, Rojo J, Romero-Salguero F J, et al. Angew. Chem. Int. Ed., 2004, 43:3644-3662
-
[3]
[3] Kitagawa S, Uemura K. Chem. Soc. Rev., 2005, 34:109-119
-
[4]
[4] Zheng Y Z, Xue W, Zheng S L, et al. Adv. Mater., 2008, 20: 1534-1538
-
[5]
[5] Wang X Y, Wei H Y, Wang Z M, et al. Inorg. Chem., 2005, 44:572-583
-
[6]
[6] Escuer A, Cano J, Goher M A S, et al. Inorg. Chem., 2000, 39:4688-4695
-
[7]
[7] Cheng X N, Zhang W X, Chen X M. J. Am. Chem. Soc., 2007, 129:15738-15739
-
[8]
[8] Cheng X N, Xue W, Huang J H, et al. Dalton Trans., 2009: 5701-5707
-
[9]
[9] Koelsch C F. J. Am. Chem. Soc., 1931, 53:304-305
-
[10]
[10] Christopher J C, Carrell H L, Jonah E, et al. J. Am. Chem. Soc., 1988, 110:8651-8656
-
[11]
[11] Lefebvre J, Trudel S, Hill R H, et al. Chem. Eur. J., 2008, 14:7156-7167
-
[12]
[12] LIU Zhong-Yi(刘忠义), LIU Jing(刘婧), YANG Na(杨娜), et al. Science China(中国科学:化学), 2013, 43:1251-1261
-
[13]
[13] Fisher M E. Am. J. Phys., 1964, 32:343-351
-
[14]
[14] Bai S Q, Gao E Q, He Z, New J. Chem., 2005, 29:935-941
-
[1]
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