Citation: WANG Xin-Miao, WU Wei-Ping, JIANG Ya-Hui, YANG Guo-Ping, XI Zheng-Ping*. Six Lanthanide-Coordination Polymers Based on 2-Fluoroisonicotinic Acid：Synthesis, Structure, Luminescence and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 192-203. doi: 10.11862/CJIC.2014.086 shu

Six Lanthanide-Coordination Polymers Based on 2-Fluoroisonicotinic Acid：Synthesis, Structure, Luminescence and Magnetic Properties

1.
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China

Received Date: 13 November 2013
Available Online: 22 November 2013
Fund Project:

Six new 1D lanthanide-based coordination polymer helical chains with formulas of {[Ln(FINA)₃(H₂O)₂]·H₂O}_n (Ln=Pr (1), Nd (2), Eu (3), Gd (4)), {[Dy(FINA)₃(H₂O)₂]}_n (5), and {[Gd(FINA)₂(phen)(OH)]}_n (6) (HFINA=2-Fluoroisonicotinic acid, phen=1,10-phenthroline), were synthesized and structurally characterized. It is the first time that 2-Fluoroisonicotinic acid is employed in producing coordination polymers. Carboxylate moieties of the ligand in these compounds exhibit two types of coordination modes because of the lanthanide contraction effect. Ln³⁺ ion is coordinated by eight donor atoms in a distorted bicapped trigonal-prismatic arrangement in 1~4 while in distorted dodecahedron geometry in 5~6. All of helical chains are further extended via the intermolecular π…π interactions, strong O-H…O/Nhydrogen bonds and C-H…F hydrogen bonds into a 3D supramolecular structures. Interestingly, in 1~4, there is a small 1D solvent channel along the b-axis, where water molecules are located. The luminescence properties of 3 and 4 have been investigated and the result indicate that compound 3 displays intense red luminescence and exhibits the characteristic transition of the Eu³⁺ ion with a decay lifetime of 333.81 μs, while 4 would be attributed to the intraligand fluorescence, based on the emission spectrum of the free ligand. The magnetic properties of 2~6 reveal the weak antiferromagnetic characters. Additionally, the thermal analyses suggest the high thermal stability of compounds 1~6.
- lanthanide-coordination polymers;2-fluoroisonicotinic acid;helical chains;luminescence;magnetism,
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沈阳化工大学材料科学与工程学院沈阳 110142