Citation: ZOU Ji-Yong, SHI Wei, GAO Hong-Ling, CUI Jian-Zhong, CHENG Peng*. A Hexanuclear CoⅡ Complex Assembled with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid:Synthesis, Crystal Structure and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 149-154. doi: 10.11862/CJIC.2014.085
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Anew hexanuclear CoⅡ complex, namely [Co6(TDA)4(H2O)14]·5H2O (1) (H3TDA=1H-1,2,3-triazole-4,5-dicarboxylic acid), has been successfully synthesized and characterized by infrared spectra, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffraction. Complex 1 crystallizes in orthorhombic space group P21212, with cell parameters: a=1.64730(2) nm, b=1.65330(2) nm, c=0.732690(10) nm and Flack parameter of 0.00(13). In title complex, six CoⅡ ions are connected by four TDA3- ligands to form a hexanuclear CoⅡunit, which can be extended to a 3D supramolecular architecture through the hydrogen-bonding interactions. Magnetic study reveals the dominant antiferromagnetic interaction exist between CoⅡ ions in 1.
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