Citation: ZOU Ji-Yong, SHI Wei, GAO Hong-Ling, CUI Jian-Zhong, CHENG Peng*. A Hexanuclear Co^Ⅱ Complex Assembled with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid：Synthesis, Crystal Structure and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 149-154. doi: 10.11862/CJIC.2014.085 shu

A Hexanuclear Co^Ⅱ Complex Assembled with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid：Synthesis, Crystal Structure and Magnetic Property

1.
1 Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), and Synergetic Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China;

Received Date: 30 September 2013
Available Online: 12 December 2013
Fund Project:

Anew hexanuclear Co^Ⅱ complex, namely [Co₆(TDA)₄(H₂O)₁₄]·5H₂O (1) (H₃TDA=1H-1,2,3-triazole-4,5-dicarboxylic acid), has been successfully synthesized and characterized by infrared spectra, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffraction. Complex 1 crystallizes in orthorhombic space group P2₁2₁2, with cell parameters: a=1.64730(2) nm, b=1.65330(2) nm, c=0.732690(10) nm and Flack parameter of 0.00(13). In title complex, six Co^Ⅱ ions are connected by four TDA^3- ligands to form a hexanuclear Co^Ⅱunit, which can be extended to a 3D supramolecular architecture through the hydrogen-bonding interactions. Magnetic study reveals the dominant antiferromagnetic interaction exist between Co^Ⅱ ions in 1.
- 1H-1,2,3-triazole-4,5-dicarboxylic acid;hexanuclear Co^Ⅱ unit;crystal structure;antiferromagnetic interaction,
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A Hexanuclear CoⅡ Complex Assembled with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid：Synthesis, Crystal Structure and Magnetic Property

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通讯作者: 陈斌, bchen63@163.com

A Hexanuclear Co^Ⅱ Complex Assembled with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid：Synthesis, Crystal Structure and Magnetic Property