Citation: WANG Hui, CHAI Zhi-Fang, WANG Dong-Qi*. Interactions between Humic Acids and Actinides：Recent Advances[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 37-52. doi: 10.11862/CJIC.2014.084 shu

Interactions between Humic Acids and Actinides：Recent Advances

1.
CAS Key Laboratory of Nuclear Radiation and Nuclear Energy Techniques, and Multidisciplinary Initiative Center, Institute of High energy Physics, Chinese Academy of Sciences, Beijing 100049, China

Received Date: 9 October 2013
Available Online: 28 October 2013
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Recent advances on the experimental and computational studies of interactions between humic acids (HAs) and actinides are briefly reviewed. It appears that HAs are able to form coordination complexes with actinide cations (Anⁿ⁺) mainly via their carboxylate groups, and as a consequence, influence the migration of Anⁿ⁺. In geomedia, many factors may affect the interactions between HA and Anⁿ⁺, including pH, ionic strength, mineral surfaces, among which the effect of pH is the most significant. In general, at low pH, HA may enhance the adsorption of Anⁿ⁺ on the surface of minerals, while when pH is around or larger than₇, HA plays an opposite role. In addition, HAs may reduce high valent oxidative actinide cations, and the reductivity originates from their quinoid and phenol groups. In those HAs with high presence of reduced sulfur, HAs may become more redox sensitive due to the participation of Sin the redox reactions. The paper is concluded with an outlook.
- humic acids;metallic ions;actinide cations;coordination chemistry,
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