Citation: HUANG Yin, MENG Xiang-Gao, QIN Jin-Gui*. Synthesis, Crystal Structure and Nonlinear Optical Property of K2W3SeO12[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 179-184. doi: 10.11862/CJIC.2014.082
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K2W3SeO12 was synthesized by hydrothermal method. It crystallizes in space group R3c of the rhombohedral system, with cell parameters a=b=c=1.25361(10) nm, α=β=γ=33.5390(10)°. It was further characterized by the tests of XRD, EDX, ATR-FTIR, UV-Vis-NIR, TGand SHG (second harmonic generation). Its powders show a phase-matchable SHG response of approximately 9 times of KDP. It also exhibits wide band gap (3.24 eV) and good thermal stability. Its infrared absorption wavelength can reach up to 10 μm. Therefore, K2W3SeO12 is regarded as a promising candidate for NLO (nonlinear optical) materials in the mid-IRregion.
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