Citation: HUANG Yin, MENG Xiang-Gao, QIN Jin-Gui*. Synthesis, Crystal Structure and Nonlinear Optical Property of K₂W₃SeO₁₂[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 179-184. doi: 10.11862/CJIC.2014.082 shu

Synthesis, Crystal Structure and Nonlinear Optical Property of K₂W₃SeO₁₂

1.
1 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China;

Received Date: 1 November 2013
Available Online: 27 November 2013
Fund Project:

K₂W₃SeO₁₂ was synthesized by hydrothermal method. It crystallizes in space group R3c of the rhombohedral system, with cell parameters a=b=c=1.25361(10) nm, α=β=γ=33.5390(10)°. It was further characterized by the tests of XRD, EDX, ATR-FTIR, UV-Vis-NIR, TGand SHG (second harmonic generation). Its powders show a phase-matchable SHG response of approximately 9 times of KDP. It also exhibits wide band gap (3.24 eV) and good thermal stability. Its infrared absorption wavelength can reach up to 10 μm. Therefore, K₂W₃SeO₁₂ is regarded as a promising candidate for NLO (nonlinear optical) materials in the mid-IRregion.
- tungsten selenites;hydrothermal synthesis;nonlinear optical property;crystal structure;band gap,
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Nonlinear Optical Property of K2W3SeO12

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and Nonlinear Optical Property of K₂W₃SeO₁₂