Citation: ZHAO Yue, ZHAI Ling-Ling, SUN Wei-Yin*. Synthesis, Crystal Structure and Fluorescence Property of Zn(Ⅱ), Cd(Ⅱ)Coordination Polymers with Benzoimidazol-Containing Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 99-105. doi: 10.11862/CJIC.2014.081
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Two new coordination polymers [Zn(L)(m-BDC)] (1) and [Cd(L)(CCA)]·2H2O (2) were synthesized by solvothermal method using 3,5-di(1H-benzoimidazol-1-yl)pyridine (L), isophthalic acid (m-H2BDC), 4-(2-carbox-yvinyl)benzoic acid (H2CCA). And the complexes were characterized by FT-IR, elemental analysis, thermogravimetric analysis (TGA) and power X-ray diffraction (PXRD), meanwhile the crystal structures and fluorescence properties of the complexes have been studied. In complex 1, the ligand Lconnects the metal atoms to give a 1Dchain structure, and the m-BDC2- coordinates with metal atom to form a M2(m-BDC)2 unit (M=metal). Moreover, the adjacent 1D chains are linked by the M2(m-BDC)2 to produce a 2D network structure. In complex 2, the ligand joins the metal atoms to generate a 1D chain like that in 1. However, the carboxylate ligand coordinates with metal atoms to form a 1D chain, and two kinds of the 1D chains crosslink each other to produce a 2D structure.
-
-
[1]
[1] Meot-Ner M. Chem. Rev., 2005, 105:213-284
-
[2]
[2] O'Keeffe M, Yaghi O M. Chem. Rev., 2012, 112:675-702
-
[3]
[3] LI Zheng(李正), ZHAO Yue(赵越), WANG Peng(王鹏), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28:1469-1476
-
[4]
[4] Gao Q, Xie Y B, Li J R, et al. Cryst. Growth Des., 2012, 12: 281-288
-
[5]
[5] Herm Z R, Swisher J A, Smit B, et al. J. Am. Chem. Soc., 2011, 133:5664-5667
-
[6]
[6] Pan M, Lin X M, Li G B, et al. Coord. Chem. Rev., 2011, 255:1921-1936
-
[7]
[7] Swiegers G F, Malefetse T J. Chem. Rev., 2000, 100:3483-3537
-
[8]
[8] Luo L, Zhao Y, Lu Y, et al. Polyhedron, 2012, 38:88-96
-
[9]
[9] Zhao Y, Lv M F, Fan J, et al. Inorg. Chim. Acta, 2011, 377: 138-143
-
[10]
[10] Chen M, Chen M S, Okamura T, et al. CrystEngComm, 2011, 13:3801-3810
-
[11]
[11] Yang W, Schmider H, Wu Q, et al. Inorg. Chem., 2000, 39: 2397-2404
-
[12]
[12] Lin W, Wang Z, Ma L. J. Am. Chem. Soc., 1999, 121:11249-11250
-
[13]
[13] Software Packages SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison, WI, 1996.
-
[14]
[14] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
-
[15]
[15] Su Z, Xu J, Fan J, et al. Cryst. Growth Des., 2009, 9:2801-2811
-
[16]
[16] Zhu H F, Fan J, Okamura T, et al. Cryst. Growth Des., 2005, 5:289-294
-
[17]
[17] Chen S S, Bai Z S, Fan J, et al. CrystEngComm, 2010, 12: 3091-3104
-
[1]
-
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