Citation: MA Zhi-Feng, ZHANG Ying-Hui, HU Tong-Liang*, BU Xian-He. Three Cobalt(Ⅱ) Complexes Based on Isomeric Carboxylate-Based Flexible Ligands：Syntheses, Structures and Magnetism[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 204-212. doi: 10.11862/CJIC.2014.078 shu

Three Cobalt(Ⅱ) Complexes Based on Isomeric Carboxylate-Based Flexible Ligands：Syntheses, Structures and Magnetism

1.
Department of Chemistry, and Tianjin Key Laboratory of Metal & Molecule-based Material Chemistry, Nankai University, Tianjin 300071, china

Received Date: 18 November 2013
Available Online: 30 November 2013
Fund Project:

Three Co(Ⅱ) complexes based on E-3-[3-(carboxymethoxy)-phenyl]acrylic acid (H₂L¹) or E-3-[3-(carboxymethoxy)-phenyl]acrylic acid (H₂L²), namely [Co(L¹)(bpp)]_n(1), {[Co(μ₃-OH)₂(L²)₄(bpy)₂(H₂O)₄]·12H₂O}_n (2), and [Co(L²)(bpy)]_n(3) (bpp: 1,3-bi(pyridin-4-yl)propane, bpy: 4,4-bipyridine), were synthesized and characterized by elemental analysis, IR, XRPD and X-ray single-crystal structure analysis. Different coordination environment for Co(Ⅱ) ions and thereby different crystal structures and magnetism were observed for these three complexes. The magnetic properties of complexes 1 and 2 were discussed in detail.
- cobalt(Ⅱ) complexes;flexible ligands;crystal structure;magnetic property,
1. [1]
  [1] Karmakar T K, Ghosh B K, Usman A, et al. Inorg. Chem., 2005, 44:2391-2393
2. [2]
  [2] Das A, Rosair G M, Fallah M S E, et al. Inorg. Chem., 2006, 45:3301-3306
3. [3]
  [3] Chen Q, Chang Z, Bu X H, et al. Angew. Chem. Int. Ed., 2013, 52, 11550-11553
4. [4]
  [4] Hagen K S, Naik S G, Huynh B H, et al. J. Am. Chem. Soc., 2009, 131:7516-7517
5. [5]
  [5] Zeng Y F, Hu X, Bu X H, et al. Chem. Soc. Rev., 2009, 38: 469-480
6. [6]
  [6] Banerjee R, Phan A, Wang B, et al. Science, 2008, 319:939-943
7. [7]
  [7] Férey G, Mellot-Draznieks C, Serre C, et al. Acc. Chem. Res., 2005, 38:217-225
8. [8]
  [8] Wu C, Hu A, Lin W. J. Am. Chem. Soc., 2005, 127:8940-8941
9. [9]
  [9] Wu C, Lin W. Angew. Chem. Int. Ed., 2007, 46:1075-1078
10. [10]
  [10] Ma L, Mihalcik D J, Lin W. J. Am. Chem. Soc., 2009, 131: 4610-4612
11. [11]
  [11] Chen Y Q, Li G R, Bu X H, et al. Chem. Sci., 2013, 4: 3678-368
12. [12]
  [12] Zhang P, Zhang L, Lin S Y, et al. Inorg. Chem., 2013, 52: 4587-4592
13. [13]
  [13] Kaminker R, Motiei L, Gulino A, et al. J. Am. Chem. Soc., 2010, 132:14554-14561
14. [14]
  [14] Li J R, Tao Y, Bu X H, et al. Chem. Commun., 2007:1527-1529
15. [15]
  [15] Tian D, Chen Q, Bu X H, et al. Angew. Chem. Int. Edit., 2013, DOI: 10.1002/anie.201307681
16. [16]
  [16] Baur W H. Nat. Mater., 2003, 2:17-18
17. [17]
  [17] Yao X Q, Cao D P, Hu J S, et al. Cryst. Growth Des., 2011, 11:231-239
18. [18]
  [18] Thomas D, Serre C, Audebrand N, et al. J. Am. Chem. Soc., 2005, 127:1278812789
19. [19]
  [19] Seo J S, Whang D, Lee H, et al. Nature, 2000, 404:982-986
20. [20]
  [20] Ghosh S K, Zhang J P, Kitagawa S. Angew. Chem. Int. Ed., 2008, 47:3403-3406
21. [21]
  [21] Fang S M, Zhang Q, Hu M, et al. Inorg. Chem., 2010, 49: 9617-9626
22. [22]
  [22] Eliseeva S V, Pleshkov D N, Lyssenko K A, et al. Inorg. Chem., 2010, 49:9300-9311
23. [23]
  [23] Blight B A, Stewart A F, Wang N, et al. Inorg. Chem., 2012, 51:778-780
24. [24]
  [24] Zheng X Y, Ye L Q, Wen Y H. J. Mol. Struct., 2011, 987: 132-137
25. [25]
  [25] Chen L. Acta Cryst. E, 2012, 68:m882
26. [26]
  [26] Ji J, Yang Y F, Wen Y H. Acta Cryst. E, 2012, 68:m912-913
27. [27]
  [27] Sheldrick G M. SADABS, Siemens Area Detector Absorption Corrected Software, University of Gttingen, Germany, 1996.
28. [28]
  [28] Sheldrick G M. SHELXTL NT Version 5.1. Program for Solution and Refinement of Crystal Structures, University of Gttingen, Germany, 1997.
29. [29]
  [29] Liu S J, Xue L, Hu T L, et al. Dalton Trans., 2012, 41:6813-6819
30. [30]
  [30] Wang X Y, Wang Z M, Gao S. Inorg. Chem., 2008, 47:5720-5726
31. [31]
  [31] Cheng X H, Xue W, Zhang W X, et al. Chem. Mater., 2008, 20:5345-5350
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沈阳化工大学材料科学与工程学院沈阳 110142