Citation: WAN Hong-Xiang, JU Wei-Wei, ZHANG Yu, XU Yan*. Synthesis, Structures and Properties of the 3D Compounds Containing L-Chiral Helical Chains[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 85-92. doi: 10.11862/CJIC.2014.074 shu

Synthesis, Structures and Properties of the 3D Compounds Containing L-Chiral Helical Chains

1.
State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

Received Date: 12 July 2013
Available Online: 4 December 2013
Fund Project:

Two compounds with L-Chiral helical chains have been solvothermal synthesized: Sm(HCO₂)(SO₄)(H₂O) (1) and KSm(H₂O)(SO₄)₂ (2). Complex 1 is synthesized without any chiral auxiliary, while complex 2 is the opposite. However, in 2, chiral auxiliaries do not exsit in the inorganic framework but work as the inducer in the formation of the complex. Single-crystal X-ray diffraction (XRD) demonstrates that complex 1 crystallizes in space group P4₁ and complex 2 crystallizes in space group P3₁. Complex 1 is constructed of two types of L-[Sm-O]_n chains, every two different kinds of adjacent helical chains are connected by sharing Sm(Ⅲ) ions to form Intertwined left-handed double helices. Compound 2 is constructed of two L-chiral helical chains: [Sm-O-S₁-O]_n and [Sm-O-S₂-O]_n, the two adjacent helical chains are connected by sharing Sm(Ⅲ) ions to form double helices chains, every two adjacent double helices chains are connected through K⁺ linkages to form Intertwined left-handed double helices. The second-harmonic-generation efficiencies and fluorescence of 1 and 2 were studied.
- solvothermal synthesis;chirality;fluorescence;second-harmonic generation effect,
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沈阳化工大学材料科学与工程学院沈阳 110142