Citation: LIU Jin-Jian, LIU Zu-Liang, CHENG Jian. Synthesis, Crystal Structure and Catalytic Properties of Two Energetic Complexes Containing 2,6-Diamino-3,5-dinitropyrazine-1-oxide[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 696-704. doi: 10.11862/CJIC.2014.064
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Two energetic complexes with 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) [Cu4O2 (C4N6O5H2)2(CH3COO)2(DMF)2]·DMF(1)((C4N6O5H2)2-is obtained by losing two protons from LLM-105) and [Co(C4N6O5H3)3]·7H2O(2) ((C4N6O5H3)- is obtained by losing a proton from LLM-105) have been synthesized and structurally characterized using X-ray diffraction. The results reveal that complex 1 belongs to the orthorhombic system (space group Pbca) and complex 2 belongs to the trigonal system (space group R3). Thermal decomposition of LLM-105 and two complexes was examined by DSC and TG-DTG analyses. The kinetic parameters of the exothermic processes of two complexes were studied by the Kissingers and Ozawa-Doyles methods. DSC measurements show that two complexes have decreased the higher thermal decomposition temperature of AP by 117.42 and 71.85 ℃, increased the exothermic quantity of decomposition by 1 916.97 and 1 433.76 J·g-1 respectively, showing good catalytic effects on the thermal decomposition of AP. CCDC: 938305, LLM-105; 911164, 1; 911163, 2.
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