Citation: ZHANG Lai-Jun, TONG Ji-Zao, CHEN Fa-Yun, HUANG Hai-Jin, ZOU Ru-Yi, RAO Bo-Bo. Two Cadmium Complexes Constructed from Ethyl 2-Amino-4-thiazoleacetate Ligand:Crystal Structure and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 550-556. doi: 10.11862/CJIC.2014.056
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Two cadmium complexes, [CdCl2(EATA)]n(1) and [CdCl2(EATA)2](2), have been synthesized by the reaction between CdCl2·2.5H2O and ethyl 2-amino-4-thiazoleacetate (EATA), and characterized by single-crystal X-ray diffraction, elemental analysis, infrared and photoluminescence spectra. Single crystal X-ray diffraction analysis reveals that, complex 1 crystallizes in monoclinic with space group P21/c, a=1.765 1(5) nm, b=0.927 7(3) nm, c=0.715 0(2) nm, β=92.072(5)°, V=1.170 0(6) nm3, Z=4, R1=0.0363, wR2=0.0762, S=1.082. The title complex 2 also belongs to the monoclinic system, space group Cc with a=1.686 0(3) nm, b=1.663 0(3) nm, c=1.622 0(3) nm, β=105.41(3)°, V=4.384 3(15) nm3, Z=8, R1=0.0215, wR2=0.0483, S=1.021. For either complexes 1 or 2, the central metal ion (Cd2+) displays a distorted six-coordinated octahedral geometry. In complex 1, two adjacent octahedral units are connected by two bridging μ2-Cl- anions, resulting in the formation of one-dimensional chain. These one-dimensional chains are further assembled into a three-dimensional network structure by intermolecular N-H…Cl hydrogen bonds interactions. In complex 2, two-dimensional supramolecular structure is generated via a large number of intermolecular N-H…Cl and C-H…Cl hydrogen bonds. Solid-state photoluminescence spectrum shows that complexes 1 and 2 have similar fluorescence behaviors, and both of which can be attributed to the ligand-to-metal charge transition (LMCT). CCDC: 837325, 1; 837326, 2.
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[1]
[1] Cini R, Defazio S, Tamasi G, et al. Inorg. Chem., 2007,46 (1):79-92
-
[2]
[2] Hussein B H M, Azab H A, El-Azab M F, et al. Eur. J. Med. Chem., 2012,51:99-109
-
[3]
[3] Gras M, Therrien B, Suss-Fink G, et al. J. Organ. Chem., 2010,695(8):1119-1125
-
[4]
[4] Öner H, Karatepe M, Karatas F. et al. Cell Biochem. Funct., 2005,23(6):427-433
-
[5]
[5] Thalamuthu S, Annaraj B, Vasudevan S, et al. J. Coord. Chem., 2013,66(10):1805-1820
-
[6]
[6] He Q F, Li D S, Zhao J, et al. Acta Cryst. Sect. E, 2009,65(6):m666
-
[7]
[7] Siddiqui K A, Mehrotra G K, LaDuca R L. Polyhedron, 2009,28(18):4077-4083
-
[8]
[8] Yang L, Wang Q, Li S Z. Kristallogr. -New Cryst. Struct., 2009,224:453-454
-
[9]
[9] Zhang L J, Shen X C, Yang Y. Acta Cryst. Sect. E, 2009,65 (12):m1517
-
[10]
[10] Alexandru M G, Velickovic T C, Jitaru I, et al. Cent. Eur. J. Chem., 2010,8(3):639-645
-
[11]
[11] Zhang L J, Shen X C, Liang H. Acta Cryst. Sect. E, 2008,64 (11):m1413-m1414
-
[12]
[12] ZHANG Duo(张舵), SUN Yan-Qiong(孙燕琼). J. Northeast Normal Univer. (东北师大学报), 2008,40(3):76-79
-
[13]
[13] ZHANG Dao-Jun(张道军), GUO Ye(郭晔), SHI Jing (石晶), et al. Chem. J. Chinese Universities(高等学校化学学报), 2007,28(10):1817-1820
-
[14]
[14] Zhang L J, Chen F Y, Liu G Y, et al. Acta Cryst. Sect. E, 2012,68(6):m788-m789
-
[15]
[15] LIU Chao(刘超), SUN Hui(孙辉), YANG Xiao-Liang (杨晓亮), et al. Chinese J. Inorg. Chem. (无机化学学报), 2011,27(11):2121-2127
-
[1]
-
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