Citation: CHEN Zhi-Min, YANG Ying-Qun, YI Zheng-Ji. Crystal Structure, Electrochemical, Fluorescent and Magnetic Properties of a New Manganese (Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid as a Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 659-663. doi: 10.11862/CJIC.2014.055 shu

Crystal Structure, Electrochemical, Fluorescent and Magnetic Properties of a New Manganese (Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid as a Ligand

1.
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 19 February 2013
Available Online: 20 September 2013
Fund Project: 湖南省科学技术厅科技计划项目(No.2012GK3030) (No.2012GK3030)湖南省教育厅科学研究项目(No.11C0186) (No.11C0186)衡阳市科技计划项目(No.2011kG28) (No.2011kG28)

A new complex Mn(L)₂(2,2'-bipy)₂ (1) with 2-(4-methylbenzoyl)benzoic acid (HL) as a ligand has been synthesized. Crystal data for 1 are as follows: monoclinic, space group P2₁/c, a=1.719 8(2) nm, b=1.039 80(14) nm, c=2.346 3(3) nm, β=95.732(3)°, V=4.174 8(9) nm³, D_c=1.346 g·cm^-3, Z=4, μ(Mo Kα)=0.373 mm^-1, F(000)=1 756, final discrepancy factors R₁=0.042 3, wR₂=0.094 9. In 1, Mn(Ⅱ) ion is coordinated by six atoms to give a distorted octahedral coordination geometry. The electrochemical, luminescence and magnetic properties of 1 are studied. The results show that the electron transfer of 1 is quasi reversible in the electrode reaction corresponding to Mn(Ⅲ)/Mn(Ⅱ), and 1 exhibits one relatively strong fluorescent emission band at around 536~556 nm. In addition, 1 displays antiferromagnetic property in temperatures range of 300~2 K. CCDC: 924900.
- manganese(Ⅱ) complex;2-(4-methylbenzoyl)benzoic acid;crystal structure;electrochemical;fluorescent and magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142