Citation: CHEN Zhi-Min, YANG Ying-Qun, YI Zheng-Ji. Crystal Structure, Electrochemical, Fluorescent and Magnetic Properties of a New Manganese (Ⅱ) Complex with 2-(4-Methylbenzoyl)benzoic Acid as a Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 659-663. doi: 10.11862/CJIC.2014.055
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A new complex Mn(L)2(2,2'-bipy)2 (1) with 2-(4-methylbenzoyl)benzoic acid (HL) as a ligand has been synthesized. Crystal data for 1 are as follows: monoclinic, space group P21/c, a=1.719 8(2) nm, b=1.039 80(14) nm, c=2.346 3(3) nm, β=95.732(3)°, V=4.174 8(9) nm3, Dc=1.346 g·cm-3, Z=4, μ(Mo Kα)=0.373 mm-1, F(000)=1 756, final discrepancy factors R1=0.042 3, wR2=0.094 9. In 1, Mn(Ⅱ) ion is coordinated by six atoms to give a distorted octahedral coordination geometry. The electrochemical, luminescence and magnetic properties of 1 are studied. The results show that the electron transfer of 1 is quasi reversible in the electrode reaction corresponding to Mn(Ⅲ)/Mn(Ⅱ), and 1 exhibits one relatively strong fluorescent emission band at around 536~556 nm. In addition, 1 displays antiferromagnetic property in temperatures range of 300~2 K. CCDC: 924900.
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