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Citation: LIU Xiao-Feng, MI Chang-Huan, ZHANG Wen-Qing. Preparation and Electrochemical Lithium Storage of 3D α-Fe2O3/Nitrogen-Doped Graphene/Carbon Nanotubes Nanocomposites[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 242-250. doi: 10.11862/CJIC.2014.048 shu

Preparation and Electrochemical Lithium Storage of 3D α-Fe2O3/Nitrogen-Doped Graphene/Carbon Nanotubes Nanocomposites

  • 1.

    College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

  • Corresponding author: MI Chang-Huan, 
  • Received Date: 5 August 2013
    Available Online: 26 September 2013

    Fund Project:

  • To solve the main obstacles associated with the charge-discharge process of α-Fe2O3 anode, such as serious volume expansion and low initial coulombic efficiency, 3D porous α-Fe2O3/nitrogen-doped graphene(N-GNS)/carbon nanotubes(CNTs) nanocomposites were synthesized via a facile hydrothermal method. The nanocomposites were characterized by XRD, SEM, TEM and XPS measurements and the results indicated that CNTs were successfully inserted into the interlamination between N-GNS, providing more defects than pristine GNS for α-Fe2O3 nucleating and the lithium ion storage. α-Fe2O3 nanoparticles with an average size of 30~70 nm were uniformly anchored in 3D N-GNS/CNTs carbon matrix and reacted with lithium ion efficiently. The electrochemical test results showed that this 3D composite structure can significantly improve the electrochemical performance of α-Fe2O3/GNS anode.
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