Citation: HUANG Yao, ZHOU Ming-Shan, ZHU Chao, LIU Long-Jiang, ZHOU Xiao-Jun, ZHANG Yong-Ming, FU Fei-E, JIN E. Synthesis, Structures and Luminescence Property of a 3D Zinc Coordination Polymer Based on 3, 5-Dimethyl-1H-1, 2, 4-triazole and 1,4-Benzenedicarboxylate Dianion[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 901-906. doi: 10.11862/CJIC.2014.045
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Anew zinc(Ⅱ) coordination polymer {[Zn3(Hdmtrz)2(1,4-bdc)3]·2H2O}n (1), where Hdmtrz=3,5-dimethyl-1-H-1,2,4-triazole and 1,4-bdc=1,4-benzenedicarboxylate dianion, has been prepared by hydrothermal method and structurally characterized by elemental analysis, infrared spectra, X-ray powder diffraction, thermogravimetric analysis and single-crystal X-ray diffraction. The title compound crystallizes in triclinic, space group P1 with a=0.91797(18) nm, b=0.9833(2) nm, c=1.0717(2) nm, α=100.81(3)°, β=102.589(3)°, γ=106.90(3)°, V=0.8418(3) nm3, Z=1, and compound 1 shows a 3D framework with Schläfli symbols of {412·63} which is a typical pcu(α-Po) structure. The zinc(Ⅱ) complex exhibits strong fluorescence absorption at 471 nm (λmax) in the solid state at room temperature.
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