Citation: OU Guang-Chuan, HUANG Zhong-Wen, PAN Ze-Yi, ZHOU Dong-Lai, LI Zhi-Zhang, YUAN Xian-You. Synthesis and Structure of a Three-Dimensional Polyoxovanadate-Bridged Macrocyclic Copper Complex[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 419-424. doi: 10.11862/CJIC.2014.043 shu

Synthesis and Structure of a Three-Dimensional Polyoxovanadate-Bridged Macrocyclic Copper Complex

1.
Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425199, China

Corresponding author: OU Guang-Chuan, YUAN Xian-You,
Received Date: 25 April 2013
Available Online: 18 October 2013
Fund Project:

Athree-dimensional transition metal copper macrocyclic complex {[CuL][VO₃]₂·0.67H₂O}_n (L=5,12-dimethyl^-1,8-dihydroxyethyl^-1,3,6,8,10,13-hexaazacyclotetradecane) has been isolated from the reactions of [CuL](ClO₄)₂ with NH₄VO₃, and structurally characterized by elemental analysis, IR, TG, UVspectrum and X-ray diffraction. The title compound crystallizes in the trigonal system, space group R3 with a=1.6877(12) nm, b=1.6877(12) nm, c=2.1630(3) nm, M_r=591.90, V=5.3354(10) nm³, Z=9, D_c=1.654 g·cm^-3, F(000)=2739, μ=1.714 mm^-1, the final R=0.0470 and wR=0.1347. The Cu(Ⅱ) atom lies on an inversion center and is octahedrally coordinated by four nitrogen atoms of the tetradentate macrocyclic Lligand in the equatorial plane and two oxygen atoms of [VO₄] tetrahedrons in axial positions. The title compound shows a three-dimensional structure, which is constructed by the links of hexanuclear [V₆O₁₈]^6- rings with [CuL]²⁺, forming one-dimensional channels occupied by guest water molecules. CCDC: 902742.
- macrocyclic copper complex;polyoxovanadate;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142