Citation: OU Guang-Chuan, HUANG Zhong-Wen, PAN Ze-Yi, ZHOU Dong-Lai, LI Zhi-Zhang, YUAN Xian-You. Synthesis and Structure of a Three-Dimensional Polyoxovanadate-Bridged Macrocyclic Copper Complex[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 419-424. doi: 10.11862/CJIC.2014.043
-
Athree-dimensional transition metal copper macrocyclic complex {[CuL][VO3]2·0.67H2O}n (L=5,12-dimethyl-1,8-dihydroxyethyl-1,3,6,8,10,13-hexaazacyclotetradecane) has been isolated from the reactions of [CuL](ClO4)2 with NH4VO3, and structurally characterized by elemental analysis, IR, TG, UVspectrum and X-ray diffraction. The title compound crystallizes in the trigonal system, space group R3 with a=1.6877(12) nm, b=1.6877(12) nm, c=2.1630(3) nm, Mr=591.90, V=5.3354(10) nm3, Z=9, Dc=1.654 g·cm-3, F(000)=2739, μ=1.714 mm-1, the final R=0.0470 and wR=0.1347. The Cu(Ⅱ) atom lies on an inversion center and is octahedrally coordinated by four nitrogen atoms of the tetradentate macrocyclic Lligand in the equatorial plane and two oxygen atoms of [VO4] tetrahedrons in axial positions. The title compound shows a three-dimensional structure, which is constructed by the links of hexanuclear [V6O18]6- rings with [CuL]2+, forming one-dimensional channels occupied by guest water molecules. CCDC: 902742.
-
-
[1]
[1] Udomvech A, Kongrat P, Pakawatchai C, et al. Inorg. Chem. Commun., 2012,17:132-136
-
[2]
[2] Chen L, Jiang F L, Lin Z Z, et al. J. Am. Chem. Soc., 2005, 127:8588-8589
-
[3]
[3] Gao Y Z, Xu Y Q, Gao Y, et al. Dalton Trans., 2012,41:567- 571
-
[4]
[4] Liu S, Xie L, Gao B, et al. Chem. Commun., 2005,40:5023- 5025
-
[5]
[5] Khan M I, Yohannes E, Doedens R J. Inorg. Chem., 2003, 42:3125-3129
-
[6]
[6] Zhang X M, Tong M L, Chen X M. Chem. Commun., 2000: 1817-1818
-
[7]
[7] Zhang L, Schmitt W. J. Am. Chem. Soc., 2011,133:11240 -11248
-
[8]
[8] Xie Y P, Mak T C W. Chem. Commun., 2012,48:1123-1125
-
[9]
[9] Ou G C, Jiang L, Feng X L, et al. Dalton Trans., 2009:71- 76
-
[10]
[10] Ou G C, Yuan X Y, Li Z Z. Transit. Met. Chem., 2012,37: 705-711
-
[11]
[11] Ou G C, Yuan X Y, Li Z Z. Chinese J. Struct. Chem., 2013,32(3):375-380
-
[12]
[12] Ou G C, Yuan X Y, Li Z Z. J. Coord. Chem., 2013,66(12): 2065-2075
-
[13]
[13] Curtis N F. J. Chem. Soc. (A), 1960:4409-4413
-
[14]
[14] Curtis N F, Curtis Y M, Powell E J K. J. Chem. Soc. (A), 1966:1015-1018
-
[15]
[15] Tait A M, Busch D H. Inorg. Synth., 1978,18:4-6
-
[16]
[16] Zhang B, Kou H Z, Cui A L, et al. Chinese J. Struct. Chem., 2005,24:1259-1263
-
[17]
[17] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data; University of Göttingen: Göttingen, 1996.
-
[18]
[18] Sheldrick G M. Acta Cryst., 2008,A64:112-122
-
[19]
[19] Brown I D, Altermatt D. Acta Crystallogr. B, 1985,41:244-247
-
[20]
[20] Spek A L. J. Appl. Crystallogr., 2003,36:7-13
-
[21]
[21] Pope M T. Heteropoly and Isopoly Oxometalates. New York: Springer Verlag, 1983.
-
[22]
[22] Weakley T I R. Struct. Bond., 1974,18:131-135
-
[23]
[23] Crews P, Rodriguez J, Jaspars M. Organic Structure Analysis. Oxford: Oxford University Press, 1998.
-
[24]
[24] Mohamed G G, El-Gamel N E A. Spectrchim. Acta, Part A, 2004,60:3141-3154
-
[25]
[25] LI Xiu-Mei(李秀梅), JI Jian-Ye(纪建业), NIU Yan-Ling (牛艳玲), et al. Chinese J. Inorg. Chem. (无机化学学报), 2013,29:1302-1306
-
[1]
-
-
[1]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[2]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[3]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[4]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[5]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[6]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[7]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[8]
Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
-
[9]
Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
-
[10]
Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
-
[11]
Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
-
[12]
Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
-
[13]
Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu2+. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
-
[14]
Shuyan ZHAO . Field-induced CoⅡ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
-
[15]
Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
-
[16]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[17]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[18]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[19]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[20]
Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(596)
- HTML views(18)