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Citation: CHEN Sheng, HAN Jian-Lin*, LI Gui-Gen, PAN Yi*. K2CO3/Ni(OAc)2 Catalyzed Aminobromination of β-Methyl-β-nitrostyrenes with Benzamide/N, N-Dibromobenzamide as Nitrogen/Bromine Source[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 213-219. doi: 10.11862/CJIC.2014.042 shu

K2CO3/Ni(OAc)2 Catalyzed Aminobromination of β-Methyl-β-nitrostyrenes with Benzamide/N, N-Dibromobenzamide as Nitrogen/Bromine Source

  • 1.

    1 School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination, Nanjing University, Nanjing 210093, China;

  • Received Date: 24 June 2013
    Available Online: 24 October 2013

    Fund Project:

  • An efficient and facile aminobromination reaction of β-methyl-β-nitrostyrenes with PhCONH2/PhCONBr2 as nitrogen/bromine source has been developed, which could tolerate a wide scope of substrates with good chemical yield and diastereoselectivity. This aminobrominaiton system uses metal salt and base as the co-catalyst, which is different from our previous reported systems.
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