Citation: CHAN Chung-Sum, CHAN Kin-Shing*. Aldehydic Carbon-Hydrogen Bond Activation with Iridium(Ⅲ) Porphyrin β-Hydroxyethyl[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 75-84. doi: 10.11862/CJIC.2014.034 shu

Aldehydic Carbon-Hydrogen Bond Activation with Iridium(Ⅲ) Porphyrin β-Hydroxyethyl

1.
Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China

Received Date: 10 July 2013
Available Online: 6 November 2013
Fund Project:

Iridium(Ⅲ) porphyrin β-hydroxyethyl, Ir^Ⅲ(ttp)CH₂CH₂OH (ttp=5,10,15,20-tetratolylporphyrinato dianion), was found to selectively cleave the aldehydic carbon-hydrogen bonds of aryl aldehydes giving iridium acyl complexes. Iridium acyl complexes are good candidates for the studies on carbonylation and decarbonylation reactions as well as potential functionalization. The carbon-hydrogen bond activation (CHA) is proposed to occur through the initial β-hydroxyl elimination of Ir^Ⅲ(ttp)CH₂CH₂OH to give Ir^Ⅲ(ttp)OH, which then undergoes σ-bond metathesis with the aldehydic C-H bond.
- coordination, iridium, carbonylation and decarbonylation reaction,
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沈阳化工大学材料科学与工程学院沈阳 110142