Citation: ZHANG Rui, XING Yong-Heng, TIAN Chun-Yan, WANG Xuan, GUAN Qing-Lin, HOU Ya-Nan, WANG Xin-Yu, BAI Feng-Ying. Synthesis, Structures and Spectrum Study of Copper Complexes with Triazine-Pyrazole Derivativ[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 264-270. doi: 10.11862/CJIC.2014.031 shu

Synthesis, Structures and Spectrum Study of Copper Complexes with Triazine-Pyrazole Derivativ

1.
1 College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China;

Corresponding author: XING Yong-Heng, BAI Feng-Ying,
Received Date: 27 April 2013
Available Online: 28 October 2013
Fund Project:

Two copper complexes: Cu₂(mpz^*eaT-EtO)₂(N₃)₂Cl₂ (1) and Cu₂(mpz^*eaT-MeO)₂(N₃)₄ (2) (mpz^*eaT-EtO=2-(3,5-dimethyl pyrazole)-4-ethanol-6-diethylamine-1,3,5-triazine, mpz^*eaT-MeO=2-(3,5-dimethyl pyrazole)-4-methanol-6-diethylamine-1,3,5-triazine) were synthesized with the tridentate chelate triazine-pyrazole derivative 2,4-di(3,5-dimethyl pyrazole)-6-diethylamine-1,3,5-triazine (bpz^*eaT) in the anhydrous ethanol and anhydrous methanol system, respectively. The complexes were characterized by elemental analysis, IR spectroscopy, UV spectrum thermal gravimetric analyses and single crystal X-ray diffraction. The crystal of complex 1 belongs to triclinic system, Space group P1, a=0.994 9(2) nm, b=1.021 6(2) nm, c=1.148 0(2) nm, α=115.11(3)°, β=106.99(3)°, γ=100.39(3)°, V=0.9460(3) nm³, Z=1; The crystal of complex 2 belongs to Monoclinic, Space group P2_1/c, a=1.546 4(5) nm, b=1.400 8(5) nm, c=0.890 5(3) nm, β=103.227(5)°, V=1.877 9(10) nm³, Z=2. Structural analyses have revealed that the center copper atom is five-coordinated to form distorted pyramidic geometry. CCDC: 935290, 1; 935291, 2.
- copper complex;1,3,5-triazine derivative;synthesis;structure;spectrum
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沈阳化工大学材料科学与工程学院沈阳 110142