Citation: WANG Jing-Lin, JIAO Yong, YANG Bin-Sheng. Supramolecule Assembled from Sulfonyl Hydrazone Ni(Ⅱ) Complex via π…π and C-H…π Interactions[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 411-418. doi: 10.11862/CJIC.2014.030
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An intriguing supramolecular complex NiL2 (HL: (E)-4-methyl-N'-(pyridin-2-ylmethylene) benzenesul-fonohydrazide) with novel Ni-O (sulfonyl) coordination bond has been synthesized and characterized. The structural studies indicate that two types of dimers are assembled via intermolecular offset face-to-face π…π stacking (OFF) and edge-to-face C-H…π (EF) interactions between two pyridyl rings in the crystal structure of NiL2. Each dimer exists in two enantiomeric forms. The DFTcalculation indicates that the parallel fourfold aryl embrace (P4AE) interactions, with one OFFinteraction and two EFinteractions, are stronger than that of only OFF, which can be called synergistic effects. The spectral studies show that the ratio of Ni(Ⅱ) to HLis 1:2 in this compound. CCDC: 773667.
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-
[1]
[1] Steed J W, Atwood J L. Supramolecular Chemistry. 2nd Ed. Chichester: John Wiley & Sons, Ltd., 2009:2-9
-
[2]
[2] Leininger S, Olenyuk B, Stang P J. Chem. Rev., 2000,100: 853-908
-
[3]
[3] LI Zheng(李正), ZHAO Yue(赵越), WANG Peng(王鹏), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(7): 1469-1476
-
[4]
[4] Huang W, Zhu H B, Gou S H. Coord. Chem. Rev., 2006, 250:414-423
-
[5]
[5] Tiefenbacher K, Rebek Jr J. J. Am. Chem. Soc., 2012,134: 2914-2017
-
[6]
[6] Desiraju G R. Angew. Chem. Int. Engl., 1995,34:2311-2327
-
[7]
[7] NI Zhong-Hai(倪中海), NIE Jing(聂景), LI Guo-Ling(李国 玲), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(2):411-416
-
[8]
[8] Quiñonero D, Frontera A, Escudero D, et al. Theor. Chem. Account, 2008,120:385-393
-
[9]
[9] Wei W, Wu M, Gao Q, et al. Inorg. Chem., 2009,48:420-422
-
[10]
[10] Dance I, Scudder M. CrystEngComm, 2009,11:2233-2247
-
[11]
[11] Russell V, Scudder M, Dance I. J. Chem. Soc., Dalton Trans., 2001:789-799
-
[12]
[12] McMurtrie J, Dance I. CrystEngComm, 2005,7:216-229
-
[13]
[13] Dance I. New J. Chem., 2003,27:22-27
-
[14]
[14] Dance I. CrystEngComm, 2003,5:208-221
-
[15]
[15] Lacour J, Bernardinelli G, Russell V, et al. CrystEngComm, 2002,4(30):165-170
-
[16]
[16] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896
-
[17]
[17] Wang J, Liu B, Yang B. CrystEngComm, 2011,13:7086- 7097
-
[18]
[18] Döring M, Görls H, Uhlig E. Z. Anorg. Allg. Chem., 1992, 613:55-59
-
[19]
[19] Larabi L, Harek Y, Reguig A, et al. J. Serb. Chem. Soc., 2003,68(2):85-95
-
[20]
[20] (a)SMART (control) and SAINT (integration) Software, Bruker Analytical X-ray Systems, Madison, WI, 1994. (b)Bruker, SMART(Version 5.0) and SAINT (Version 6.02), Bruker AXS Inc., Madison, Wisconsin, USA, 2000.
-
[21]
[21] Sheldrick G M. SADABS, A Program for Absorption Corrections, University of Göttingen, Germany, 1996.
-
[22]
[22] Sheldrick G M. SHELXL97, A Program for the Refinement of Crystal Structures from X-ray Data, University of Göttingen, Germany, 1997.
-
[23]
[23] Klaus B. DIAMOND, Version 1.2c, University of Bonn, Germany, 1999.
-
[24]
[24] Frisch M J, Trucks G W, Schlegel H B, et al. Gaussian 03, Gaussian Inc., Pittsburgh, PA, 2003.
-
[25]
[25] Chavarot M, Ménage S, Hamelin O, et al. Inorg. Chem., 2003,42:4810-4816
-
[26]
[26] Li M, Sun Q, Bai Y, et al. Dalton Trans., 2006:2572-2578
-
[27]
[27] Zuccaccia D, Bellachioma G, Cardaci G, et al. Dalton Trans., 2006:1963-1971
-
[28]
[28] Gao E Q, Yue Y F, Bai S Q, et al. J. Am. Chem. Soc., 2004,126:1419-1429
-
[29]
[29] Lakowicz J R. Principles of Fluorescence Spectroscopy. 3rd. Ed. New York: Springer Science+Business Media, LLC, 2006:334-338
-
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