Citation: ZHAO Yu-Shuang, Wang Xin-Ying, LU Ming-Jun, YU Yong, GUO Meng-Xi, YANG Xiao-Jing*. Synthesis and Photoluminescence Property of Organic Sensitizer Intercalated Layered Terbium Hydroxide Nanocomposites[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 220-226. doi: 10.11862/CJIC.2014.028 shu

Synthesis and Photoluminescence Property of Organic Sensitizer Intercalated Layered Terbium Hydroxide Nanocomposites

  • Received Date: 17 March 2013
    Available Online: 11 July 2013

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  • Deprotonated terephthalic acid (TA) and benzoic acid (BA), as sensitizers, were successfully intercalated into the layered terbium hydroxides, through ion-exchange reaction under hydrothermal condition. The photoluminescence spectra indicated that both of TA2- and BA- enhanced the characteristic green photolu-minescence emission of Tb3+ by the efficiency energy transition process between the sensitizer and Tb3+, and furthermore that the sensibilization of TA2- was much stronger than that of BA-. The mechanism of the energy transfer from the organic sensitizers to Tb3+ was discussed based on the energy level matching herein.
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