Citation: ZHAO Yu-Shuang, Wang Xin-Ying, LU Ming-Jun, YU Yong, GUO Meng-Xi, YANG Xiao-Jing*. Synthesis and Photoluminescence Property of Organic Sensitizer Intercalated Layered Terbium Hydroxide Nanocomposites[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 220-226. doi: 10.11862/CJIC.2014.028 shu

Synthesis and Photoluminescence Property of Organic Sensitizer Intercalated Layered Terbium Hydroxide Nanocomposites

1.
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China

Received Date: 17 March 2013
Available Online: 11 July 2013
Fund Project:

Deprotonated terephthalic acid (TA) and benzoic acid (BA), as sensitizers, were successfully intercalated into the layered terbium hydroxides, through ion-exchange reaction under hydrothermal condition. The photoluminescence spectra indicated that both of TA^2- and BA^- enhanced the characteristic green photolu-minescence emission of Tb³⁺ by the efficiency energy transition process between the sensitizer and Tb³⁺, and furthermore that the sensibilization of TA^2- was much stronger than that of BA^-. The mechanism of the energy transfer from the organic sensitizers to Tb³⁺ was discussed based on the energy level matching herein.
- layered terbium hydroxide;organic sensitizer;intercalation reaction;photoluminescence emission,
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沈阳化工大学材料科学与工程学院沈阳 110142