Citation: HU Chun-Yan, XIAO Wei, TAO Bai-Long, TAN Gao-Hao, YUAN Hou-Qun. Synthesis, Crystal Structures of Cu(Ⅱ) and Zn(Ⅱ) Complexes with 3,5-Dinitrobenzoic Acid and 2,2’-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 257-263. doi: 10.11862/CJIC.2014.017 shu

Synthesis, Crystal Structures of Cu(Ⅱ) and Zn(Ⅱ) Complexes with 3,5-Dinitrobenzoic Acid and 2,2’-Bipyridine Ligands

1.
Department of Chemistry, School of Science, Jiangxi Agricultural University, Nanchang 330045, China

Corresponding author: YUAN Hou-Qun,
Received Date: 3 April 2013
Available Online: 11 September 2013
Fund Project:

Four metal-organic supramolecular complexes, [Zn(3,5-dnbc)₂(2,2'-bipy)(H₂O)]·(3,5-Hdnbc) (1), [Cu(3,5-dnbc)₂(2,2'-bipy)(H₂O)] (2), [Cu(2,2'-bipy)₂(3,5-dnbc)](NO₃)·2(3,5-Hdnbc) (3), and [Cu(2,2'-bipy)₂Cl](3,5-dnbc)·(3,5-Hdnbc) (4) were obtained by the reactions of 3,5-dinitrobenzoic acid and 2,2'-bipyridine as ligands with Zn²⁺ and Cu²⁺ ions. The four complexes were characterized by elemental analysis, IR, and the crystal structures were determined by single X-ray diffraction. The complexes of 1 and 2 were characterized by thermal gravimetric analysis. All of the four complexes are mononuclear complexes. In complex 1, Zn²⁺ is five-coordination in a distorted trigonal bipyramid geometry; in complex 2, Cu²⁺ is five-coordination in a distorted tetragonal pyramid geometry; in complex 3 and 4, Cu²⁺ is five-coordination in a distorted trigonal bipyramid geometry. Hydrogen bonding and π-π interactions are observed in these complexes. CCDC: 931926, 1; 931927, 2; 931928, 3; 931929, 4.
- 3,5-dinitrobenzoic acid;2,2'-bipyridine;organic-metal complex;crystal structure
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