Citation: LIU Ming-Ming, LÜ Wen-Miao, SHI Xiu-Feng, FAN Bin-Bin, LI Rui-Feng. Characterization and Catalytic Performence of Zeolitic Imidazolate Framework-8 (ZIF-8) Synthesized by Different Methods[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 579-584. doi: 10.11862/CJIC.2014.009
-
A series of Zeolitic Imidazolate Framework-8(ZIF-8) samples was synthesized in a mixture of methanol and aqueous ammonia, methanol, and DMF, respectively (denoted as ZIF-8(NH4OH), ZIF-8(MeOH) and ZIF-8(DMF)) with 2-methylimidazole as an organic linker and Zn(OH)2 or Zn(NO3)2·6H2O as Zn source. The physicochemical properties and catalytic performance of the samples were characterized by XRD, FTIR, N2 adsorption, SEM, TPD and Knoevenagel reaction. The results show that ZIF-8 can be synthesized by three methods and the samples synthesized by different methods have similar morphologies, but different particle sizes and acid-base properties. ZIF-8(MeOH) has much narrower particle size distribution, smaller particle size as well as more acid and base centers than those of ZIF-8(NH4OH) and ZIF-8(DMF). The ZIF-8 samples exhibit significant difference in catalytic performance for Knoevenagel reaction from benzaldehyde and malononitrile. ZIF-8(MeOH) is the most effective catalyst. The higher catalytic activity of the ZIF-8(MeOH) sample is closely related with its higher external surface area and acid-base properties.
-
-
[1]
[1] Ma S, Zhou H C. Chem. Commun., 2010,46(1):44-53
-
[2]
[2] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112(2):869-932
-
[3]
[3] Dhakshinamoorthy A, Garcia H. Chem. Soc. Rev., 2012,41 (15):5262-5284
-
[4]
[4] Phan A, Doonan C J, Uribe-Romo F J, et al. Acc. Chem. Res., 2010,43(1):58-67
-
[5]
[5] Venna S R, Carreon M A. J. Am. Chem. Soc., 2010,132(1): 76-78
-
[6]
[6] Venna S R, Jasinski J B, Carreon M A. J. Am. Chem. Soc., 2010,132(51):18030-18033
-
[7]
[7] Park K S, Ni Z, Cté A P, et al. Proc. Natl. Acad. Sci. USA, 2006,103(27):10186-10191
-
[8]
[8] Luebbers M T, Wu T, Shen L, et al. Langmuir, 2010,26(19):15625-15633
-
[9]
[9] Bux H, Chmelik C, Krishna R, et al. J. Membrane. Sci., 2011, 369(1):284-289
-
[10]
[10] Jiang H L, Akita T, Ishida T, et al. J. Am. Chem. Soc., 2011,133(5):1304-1306
-
[11]
[11] Jiang H L, Liu B, Akita T, et al. J. Am. Chem. Soc., 2009, 131(32):11302-11303
-
[12]
[12] Zahmakiran M. Dalton Trans., 2012,41(41):12690-12696
-
[13]
[13] Nguyen L T L, Le K K A, Phan N T S. Chin. J. Catal.(催化学报), 2012,33(4):688-696
-
[14]
[14] Miralda C M, Macias E E, Zhu M, et al. ACS Catal., 2011,2 (1):180-183
-
[15]
[15] Chizallet C, Lazare S, Bazer-Bachi D, et al. J. Am. Chem. Soc., 2010,132(35):12365-12377
-
[16]
[16] Tran U P N, Le K K A, Phan N T S. ACS Catal., 2011,1(2): 120-127
-
[17]
[17] Sinhamahapatra A, Pal P, Tarafdar A, et al. ChemCatChem., 2013,5(1):331-338
-
[18]
[18] Zhou X, Zhang H P, Wang G Y, et al. J. Mol. Catal. A: Chem., 2013,366:43-47
-
[19]
[19] Zhu M Q, Srinivas D, Bhogeswararao S, et al. Catal. Commun., 2013,32:36-40
-
[20]
[20] Phan N T S, Jones C W. J. Mol. Catal. A: Chem., 2006,253 (1/2):123-131
-
[1]
-
-
[1]
Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C60-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
-
[2]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[3]
Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
-
[4]
Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
-
[5]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[6]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[7]
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
-
[8]
Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
-
[9]
Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
-
[10]
Xin Zhang , Junyu Chen , Xiang Pei , Linxin Yang , Liang Wang , Luona Chen , Guangmei Yang , Xibo Pei , Qianbing Wan , Jian Wang . Drug-loading ZIF-8 for modification of microporous bone scaffold to promote vascularized bone regeneration. Chinese Chemical Letters, 2024, 35(6): 108889-. doi: 10.1016/j.cclet.2023.108889
-
[11]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[12]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[13]
Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
-
[14]
Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
-
[15]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[16]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[17]
Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
-
[18]
Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
-
[19]
Zhi Wang , Lingpeng Yan , Yelin Hao , Jingxia Zheng , Yongzhen Yang , Xuguang Liu . Highly efficient and photothermally stable CDs@ZIF-8 for laser illumination. Chinese Chemical Letters, 2024, 35(10): 109430-. doi: 10.1016/j.cclet.2023.109430
-
[20]
Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(2802)
- HTML views(1150)