Citation: YIN Wen-Yu, MA Yun-Sheng, WANG Jun, TANG Xiao-Yan, YUAN Rong-Xin. Synthesis and Characterization of a Dinuclear Manganese(Ⅱ) Complex Supported by Cyclohexanecarboxylate and 2, 2’-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 671-676. doi: 10.11862/CJIC.2014.006
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[Mn2(O2CC6H11)2(bipy)4](ClO4)2(C6H11CO2H=cyclohexanecarboxylic acid; bipy=2,2'-bipyridine) was synthesized under hydrothermal condition by reactions of Mn(ClO4)2·6H2O, C6H11CO2Na and bipy. In the dinuclear cation [Mn2(O2CC6H11)2(bipy)4]2+, adjacent Mn atoms are linked together through two cyclohexanecarboxylate ligands in syn-anti bridging mode. The molecules are packed together through π-π stacking of the pyridyl groups and weak hydrogen bonding interactions of C-H…O into three-dimensional supramolecular network. Magnetic study indicates there exists weak antiferromagnetic interactions between the adjacent Mn(Ⅱ) ions. CCDC: 748489.
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