Citation: YIN Wen-Yu, MA Yun-Sheng, WANG Jun, TANG Xiao-Yan, YUAN Rong-Xin. Synthesis and Characterization of a Dinuclear Manganese(Ⅱ) Complex Supported by Cyclohexanecarboxylate and 2, 2’-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 671-676. doi: 10.11862/CJIC.2014.006 shu

Synthesis and Characterization of a Dinuclear Manganese(Ⅱ) Complex Supported by Cyclohexanecarboxylate and 2, 2’-Bipyridine Ligands

1.
Department of Chemistry & Materials Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500, China

Received Date: 22 March 2013
Available Online: 18 September 2013
Fund Project: 国家自然科学基金资助项目(No.21001018, No. 21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (BK2012643)。 (No.21001018, No. 21201025)。江苏省高校自然科学重大项目(No.12KJA150001)。江苏省科技基础研究计划 (BK2012643)

[Mn₂(O₂CC₆H₁₁)₂(bipy)₄](ClO₄)₂(C₆H₁₁CO₂H=cyclohexanecarboxylic acid; bipy=2,2'-bipyridine) was synthesized under hydrothermal condition by reactions of Mn(ClO₄)₂·6H₂O, C₆H₁₁CO₂Na and bipy. In the dinuclear cation [Mn₂(O₂CC₆H₁₁)₂(bipy)₄]²⁺, adjacent Mn atoms are linked together through two cyclohexanecarboxylate ligands in syn-anti bridging mode. The molecules are packed together through π-π stacking of the pyridyl groups and weak hydrogen bonding interactions of C-H…O into three-dimensional supramolecular network. Magnetic study indicates there exists weak antiferromagnetic interactions between the adjacent Mn(Ⅱ) ions. CCDC: 748489.
- cyclohexanecarboxylate;dinuclear manganese complex;crystal structure;magnetic property
1. [1]
  [1] Christou G. Acc. Chem. Res., 1989,22:328-335
2. [2]
  [2] Aromí G, Aubin S M J, Bolcar M A, et al. Polyhedron, 1998,17:3005-3020
3. [3]
  [3] Tasiopoulos A J, Vinslava A, Wernsdorfer W, et al. Angew.Chem. Int. Ed., 2004,43:2117-2121
4. [4]
  [4] Aromí G, Brechin E K. Struct. Bond, 2006,122:1-67
5. [5]
  [5] Zheng Y Z, Xue W, Zhang W X, et al. Inorg. Chem., 2007,46:6437-6443
6. [6]
  [6] Tasiopoulos A J, Vinslava A, Wernsdorfer W, et al. Angew. Chem. Int. Ed., 2004,43:2117-2121
7. [7]
  [7] Moushi E E, Lampropoulos C, Wernsdorfer W, et al. Inorg. Chem., 2007,46:3795-3797
8. [8]
  [8] Murugesu M, Raftery J, Wernsdorfer W, et al. Inorg. Chem.,2004,43:4203-4209
9. [9]
  [9] Soler M, Wernsdorfer W, Folting K, et al. J. Am. Chem. Soc., 2004,126:2156-2165
10. [10]
  [10] Chen Z, Ma Y, Liang F, et al. J. Organomet. Chem., 2008, 693:646-654
11. [11]
  [11] Ma Y S, Tang X Y, Xue F F, et al. Eur. J. Inorg. Chem., 2012,1243-1249
12. [12]
  [12] Chen X M, Tang Y X, Xu Z J, et al. J. Chem. Soc. Dalton Trans., 1995,4001-4004
13. [13]
  [13] Oshio O H, Ino E, Mogi I, et al. Inorg. Chem., 1993,32: 5697-5703
14. [14]
  [14] Matsushima H, Ishiwa E, Nakashima M, et al. Chem. Lett., 1995,129-130
15. [15]
  [15] Bossek U, Wieghardt K, Nuber B, et al. Inorg. Chim. Acta, 1989,165:123-129
16. [16]
  [16] Coucouvanis D, Reynolds R A, Dunham W R. J. Am. Chem. Soc., 1995,117:7570-7571
17. [17]
  [17] Pessiki P J, Khangulov S V, Ho D M, et al. J. Am. Chem. Soc., 1994,116:891-897
18. [18]
  [18] Higuchi C, Sakiyawa H, Osawa H, et al. J. Chem. Soc., Dalton Trans., 1995,4015-4020
19. [19]
  [19] Kahn O. Molecular Magnetism. New York: VCH Publishers, Inc., 1993.
20. [20]
  [20] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. New York: John Wiley and Sons, 1986.
21. [21]
  [21] Rigaku. CrystalClear. Version 1.4.0. Rigaku Corporation, Tokyo, Japan, 2005.
22. [22]
  [22] Sheldrick G M. SHELXTL/PC., Version 5.1. Bruker AXS Inc., Madison, Wisconsin, USA, 1999.
23. [23]
  [23] Albela B, Corbella M, Ribas J, et al. Inorg. Chem., 1998,37: 788-798
24. [24]
  [24] Rardin R L, Tolman W B, Lippard S J. New J. Chem., 1991,15:417-430
25. [25]
  [25] Zhang C G, Janiak C Z. Anorg. Allg. Chem., 2001,627: 1972-1975
26. [26]
  [26] Zhang Z, Liu Q L, Yang J X, et al. Trans. Metal Chem., 2003,28:930-934
27. [27]
  [27] SHEN Chao-Jun(沈超君), CHEN Jian-Shan(陈建珊), SHENG Tian-Lu(盛天录), et al. Chinese J. Struct. Chem.(结构化学), 2008,27(8):899-906
28. [28]
  [28] Fernandez G, Corbella M, Mahia J. Eur. J. Inorg. Chem., 2002,2502-2510
29. [29]
  [29] Gomez V, Corbella M. J. Chem. Crystallogr., 2011,41:843 -846
30. [30]
  [30] Huang F P, Zhang Q, Yu Q, et al. J. Chem. Res., 2011,35: 433-435
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沈阳化工大学材料科学与工程学院沈阳 110142