Citation: ZHANG Ji-Cai, LI Ying-Nan, HUANG Di, XU Fang-Yuan, CHENG Xiao-Shan, YOU Zhong-Lu. Alternate Arrangement of Cl and Br Substituent Groups in Crystal Packing：Syntheses and Structures of Schiff Bases and Their Copper(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 425-430. doi: 10.11862/CJIC.2014.004 shu

Alternate Arrangement of Cl and Br Substituent Groups in Crystal Packing：Syntheses and Structures of Schiff Bases and Their Copper(Ⅱ) Complexes

1.
1 Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China;

Corresponding author: YOU Zhong-Lu,
Received Date: 29 April 2013
Available Online: 13 September 2013
Fund Project:

Two new Schiff bases, N,N'-bis(5-chlorosalicylidene)-1,3-diaminopentane (H₂CAP) and N,N'-bis(5-bromosalicylidene)-1,3-diaminopentane (H₂BAP), and their copper(Ⅱ) complexes, [Cu(CAP)] (1), [Cu(BAP)] (2) and [Cu(CAP)_0.5(BAP)_0.5] (3), have been prepared and structurally characterized by elemental analysis, IRand electronic spectroscopy. The complexes have also been characterized by single-crystal X-ray diffraction studies. The Cu atom in each of the complexes is in a tetrahedrally distorted square planar coordination. By combination of complex 1 and 2, a new aggregation 3 was formed. There are interesting alternate arrangement of Cl and Br substituent groups in the crystal packing of the aggregation. CCDC: 889058, 1; 889059, 2; 889057, 3.
- Schiff base;copper complex;self-assembly;complex aggregation;mononuclear complex
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沈阳化工大学材料科学与工程学院沈阳 110142