Citation: LU Wen-Guan, LIU Hong-Wen, FAN Zhi-Xuan, LAI Xiu-Xia, YANG Xiao-Yun, TAN Guo-Can. Synthesis, Structure and Property of a 3D Cd(Ⅱ) Coordination Polymer Based on Mixed-Ligands of Imidazole-4,5-Dicarboxylate and 1,4-Benzenedicarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 591-596. doi: 10.11862/CJIC.2014.003 shu

Synthesis, Structure and Property of a 3D Cd(Ⅱ) Coordination Polymer Based on Mixed-Ligands of Imidazole-4,5-Dicarboxylate and 1,4-Benzenedicarboxylate

1.
Department of Chemistry, Shaoguan University, Shaoguan, Guangdong 512005, China

Received Date: 20 February 2013
Available Online: 18 September 2013
Fund Project: 国家自然科学基金(No.21071099) (No.21071099)2012年广东省大学生创新训练计划(No.gdcxcy2012-28)资助项目。 (No.gdcxcy2012-28)

Reaction of CdCl₂ with mixed-ligands of imidazole-4,5-dicarboxylic acid (H₃IDC) and 1,4-benzenedicar-boxylic acid (H₂BDC) under hydrothermal condition, yielded a new 3D cadmium(Ⅱ) coordination polymer of[Cd₂(HIDC)(BDC)(H₂O)]_n(1), which was structurally characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction. The result of single-crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the monoclinic crystal system with P2₁/n space group, a=0.884 34(2) nm, b=1.577 50(3) nm, c=1.071 58(3) nm, β=97.227(2), V=1.483 03(6) nm³, Z=4, D_c=2.513 g·cm^-3, F(000)=1 072, the final R₁=0.031 5, wR₂=0.053 1 for 2 674 observed reflections with I>2σ(I). In complex 1, the interconnection of Cd(Ⅱ) ions by carboxylate oxygen atoms from BDC^2- ligands result in an infinite 1D polymeric chain of {[Cd₂(CO₂)]₂(CO₂)₂}_n along a axis. The polymeric chains are further connected by HIDC^2- and BDC^2- bridging ligands to form a complicated 3D metal-organic framework architecture. Furthermore, its thermal stability and luminescent property at room temperature in the solid state were also investigated. CCDC: 923674.
- coordination polymer;mixed-ligands;crystal structure;luminescent property
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