Citation: LU Wen-Guan, LIU Hong-Wen, FAN Zhi-Xuan, LAI Xiu-Xia, YANG Xiao-Yun, TAN Guo-Can. Synthesis, Structure and Property of a 3D Cd(Ⅱ) Coordination Polymer Based on Mixed-Ligands of Imidazole-4,5-Dicarboxylate and 1,4-Benzenedicarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 591-596. doi: 10.11862/CJIC.2014.003
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Reaction of CdCl2 with mixed-ligands of imidazole-4,5-dicarboxylic acid (H3IDC) and 1,4-benzenedicar-boxylic acid (H2BDC) under hydrothermal condition, yielded a new 3D cadmium(Ⅱ) coordination polymer of[Cd2(HIDC)(BDC)(H2O)]n(1), which was structurally characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction. The result of single-crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the monoclinic crystal system with P21/n space group, a=0.884 34(2) nm, b=1.577 50(3) nm, c=1.071 58(3) nm, β=97.227(2), V=1.483 03(6) nm3, Z=4, Dc=2.513 g·cm-3, F(000)=1 072, the final R1=0.031 5, wR2=0.053 1 for 2 674 observed reflections with I>2σ(I). In complex 1, the interconnection of Cd(Ⅱ) ions by carboxylate oxygen atoms from BDC2- ligands result in an infinite 1D polymeric chain of {[Cd2(CO2)]2(CO2)2}n along a axis. The polymeric chains are further connected by HIDC2- and BDC2- bridging ligands to form a complicated 3D metal-organic framework architecture. Furthermore, its thermal stability and luminescent property at room temperature in the solid state were also investigated. CCDC: 923674.
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