Citation: TIAN Ai-Xiang, HOU Xue, SUN Na, XIAO Ru, YING Jun, YANG Yang, NING Ya-Li, LI Tian-Jiao, WANG Xiu-Li. Syntheses, Structures and Properties of Two POM-based Compounds Modified by Biimidazole and Its Derivative[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 839-847. doi: 10.11862/CJIC.114
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Through using two kinds of ligands (biimidazole and its derivative), two polyoxometalate-based compounds, [Ag4(biz)4][H2P2Mo5O23]·2H2O (1) and [Ag4(bbiz)4][HPW10ⅥW2ⅤO40] (2) (biz=2,2-biimidazole, bbiz=5-butyl-2,2-biimidazole), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, elemental analyses and IR spectra. Compound 1 contains bi-nuclear [Ag2(biz)2]2+ clusters, which are linked by [P2Mo5O23]6- anions through terminal O atoms to construct a 1D chain. In compound 2, each Keggin anion offers four bridging O atoms to link four bi-nuclear [Ag2(bbiz)2]2+ clusters and a 2D layer of 2 is constructed. Additionally, the electrochemical, photocatalytic and fluorescent properties of the title compounds have been studied. CCDC: 1027614, 1; 1027615, 2.
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