Citation: TIAN Ai-Xiang, HOU Xue, SUN Na, XIAO Ru, YING Jun, YANG Yang, NING Ya-Li, LI Tian-Jiao, WANG Xiu-Li. Syntheses, Structures and Properties of Two POM-based Compounds Modified by Biimidazole and Its Derivative[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 839-847. doi: 10.11862/CJIC.114 shu

Syntheses, Structures and Properties of Two POM-based Compounds Modified by Biimidazole and Its Derivative

TIAN Ai-Xiang ^1,, ,
HOU Xue ¹ ,
SUN Na ² ,
XIAO Ru ¹ ,
YING Jun ¹ ,
YANG Yang ¹ ,
NING Ya-Li ¹ ,
LI Tian-Jiao ¹ ,
WANG Xiu-Li ^1,,

1.
1 Department of Chemistry, Bohai University, Jinzhou, Liaoning 121000, China;
2.
2 Department of Chemical and Environmental Engineering, Hebei Chemical & Pharmaceutical Vocational Technology College, Shijiazhuang 050026, China

Corresponding author: TIAN Ai-Xiang, WANG Xiu-Li,
Received Date: 10 November 2014
Available Online: 22 January 2015
Fund Project: 国家自然科学基金(No.21101015,21471021,21201021)资助项目。 (No.21101015,21471021,21201021)

Through using two kinds of ligands (biimidazole and its derivative), two polyoxometalate-based compounds, [Ag₄(biz)₄][H₂P₂Mo₅O₂₃]·2H₂O (1) and [Ag₄(bbiz)₄][HPW₁₀^ⅥW₂^ⅤO₄₀] (2) (biz=2,2-biimidazole, bbiz=5-butyl-2,2-biimidazole), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, elemental analyses and IR spectra. Compound 1 contains bi-nuclear [Ag₂(biz)₂]²⁺ clusters, which are linked by [P₂Mo₅O₂₃]^6- anions through terminal O atoms to construct a 1D chain. In compound 2, each Keggin anion offers four bridging O atoms to link four bi-nuclear [Ag₂(bbiz)₂]²⁺ clusters and a 2D layer of 2 is constructed. Additionally, the electrochemical, photocatalytic and fluorescent properties of the title compounds have been studied. CCDC: 1027614, 1; 1027615, 2.
- POM-based compounds;2,2-biimidazole;5-butyl-2,2-biimidazole;electrochemical property;photocatalytic property; fluorescent property
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