引用本文:
Mengjia Luo, Yi Qiu, Zhengyang Zhou. Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4[J]. Chinese Journal of Structural Chemistry,
2025, 44(1): 100446.
doi:
10.1016/j.cjsc.2024.100446
Citation: Mengjia Luo, Yi Qiu, Zhengyang Zhou. Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4[J]. Chinese Journal of Structural Chemistry, 2025, 44(1): 100446. doi: 10.1016/j.cjsc.2024.100446
Citation: Mengjia Luo, Yi Qiu, Zhengyang Zhou. Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4[J]. Chinese Journal of Structural Chemistry, 2025, 44(1): 100446. doi: 10.1016/j.cjsc.2024.100446
Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4
摘要:
CsCdPO4 adopts a periodic 3D Cd-P-O anionic network at room temperature. As the temperature increases above 440 K, thermal vibrations induced torsion and deformation within the PO4 units are constrained by the 3D Cd-P-O network, which is critical for the unique periodic to incommensurately modulated long-range ordered phase transition.
English
Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4
Abstract:
CsCdPO4 adopts a periodic 3D Cd-P-O anionic network at room temperature. As the temperature increases above 440 K, thermal vibrations induced torsion and deformation within the PO4 units are constrained by the 3D Cd-P-O network, which is critical for the unique periodic to incommensurately modulated long-range ordered phase transition.
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