Citation: Mengjia Luo, Yi Qiu, Zhengyang Zhou. Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4[J]. Chinese Journal of Structural Chemistry, ;2025, 44(1): 100446. doi: 10.1016/j.cjsc.2024.100446 shu

Exploring temperature-driven phase dynamics of phosphate: The periodic to incommensurately modulated long-range ordered phase transition in CsCdPO4

CsCdPO4 adopts a periodic 3D Cd-P-O anionic network at room temperature. As the temperature increases above 440 K, thermal vibrations induced torsion and deformation within the PO4 units are constrained by the 3D Cd-P-O network, which is critical for the unique periodic to incommensurately modulated long-range ordered phase transition.
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