引用本文:
Jian Ji, Jie Yan, Honggen Peng. Modulation of dinuclear site by orbital coupling to boost catalytic performance[J]. Chinese Journal of Structural Chemistry,
2024, 43(8): 100360.
doi:
10.1016/j.cjsc.2024.100360
Citation: Jian Ji, Jie Yan, Honggen Peng. Modulation of dinuclear site by orbital coupling to boost catalytic performance[J]. Chinese Journal of Structural Chemistry, 2024, 43(8): 100360. doi: 10.1016/j.cjsc.2024.100360
Citation: Jian Ji, Jie Yan, Honggen Peng. Modulation of dinuclear site by orbital coupling to boost catalytic performance[J]. Chinese Journal of Structural Chemistry, 2024, 43(8): 100360. doi: 10.1016/j.cjsc.2024.100360
Modulation of dinuclear site by orbital coupling to boost catalytic performance
摘要:
This work reports on a novel ship-in-a-bottle strategy to fabricate DSCs with well-defined microstructure. The resulting DSCs exhibited outstanding performance toward catalytic ozonation of CH3SH owing to the Fe 3d orbital coupling. This is of immediate interest to the DSCs synthesis but also to the reaction mechanism investigation of catalytic ozonation. Notably, the applicability of the electron paramagnetic resonance (EPR) spectroscopy approach for determining reactive oxygen species (ROS) on the catalyst surface during ozonation processes, as well as the theoretical underpinnings for the transformation of surface oxygen species to ROS, warrant further in-depth investigation. Additionally, the use of DSCs for catalytic ozonation of a broader spectrum of VOC pollutants, beyond the specific case of CH3SH oxidation, requires comprehensive evaluation.
English
Modulation of dinuclear site by orbital coupling to boost catalytic performance
Abstract:
This work reports on a novel ship-in-a-bottle strategy to fabricate DSCs with well-defined microstructure. The resulting DSCs exhibited outstanding performance toward catalytic ozonation of CH3SH owing to the Fe 3d orbital coupling. This is of immediate interest to the DSCs synthesis but also to the reaction mechanism investigation of catalytic ozonation. Notably, the applicability of the electron paramagnetic resonance (EPR) spectroscopy approach for determining reactive oxygen species (ROS) on the catalyst surface during ozonation processes, as well as the theoretical underpinnings for the transformation of surface oxygen species to ROS, warrant further in-depth investigation. Additionally, the use of DSCs for catalytic ozonation of a broader spectrum of VOC pollutants, beyond the specific case of CH3SH oxidation, requires comprehensive evaluation.
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