引用本文:
Ping Wang, Tianbao Zhang, Zhenxing Li. Reconstruction mechanism of Cu surface in CO2 reduction process[J]. Chinese Journal of Structural Chemistry,
2024, 43(8): 100328.
doi:
10.1016/j.cjsc.2024.100328
Citation: Ping Wang, Tianbao Zhang, Zhenxing Li. Reconstruction mechanism of Cu surface in CO2 reduction process[J]. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328. doi: 10.1016/j.cjsc.2024.100328
Citation: Ping Wang, Tianbao Zhang, Zhenxing Li. Reconstruction mechanism of Cu surface in CO2 reduction process[J]. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328. doi: 10.1016/j.cjsc.2024.100328
Reconstruction mechanism of Cu surface in CO2 reduction process
摘要:
In summary, the dissolution-redeposition is the way of Cu surface reconstruction, and Cu+ species are the main intermediates driving this process. And the adsorption of molecules on the surface of Cu, forming copper adsorbate complexes, is the key to promoting the dissolution of Cu+. Among them, the formation of [CuCO]+ complex is the most favorable, which is independent of the exposed surface crystal plane structure of Cu. This work confirms the transient dissolution of Cu+ through clever experimental design, and provides theoretical guidance for future catalyst design in maintaining selectivity and activity.
English
Reconstruction mechanism of Cu surface in CO2 reduction process
Abstract:
In summary, the dissolution-redeposition is the way of Cu surface reconstruction, and Cu+ species are the main intermediates driving this process. And the adsorption of molecules on the surface of Cu, forming copper adsorbate complexes, is the key to promoting the dissolution of Cu+. Among them, the formation of [CuCO]+ complex is the most favorable, which is independent of the exposed surface crystal plane structure of Cu. This work confirms the transient dissolution of Cu+ through clever experimental design, and provides theoretical guidance for future catalyst design in maintaining selectivity and activity.
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