Citation: Shunye Yu, Yi Shui, Shuo Liu, Gan Huang, Canxiao Huang, Chunhui Geng, Lili Liu, Hongming Liu. AIO3∙H6TeO6 (A=NH4, Rb): Two Telluric Acid and Iodate Co-Crystalline Compounds with Second Harmonic Generation Response[J]. Chinese Journal of Structural Chemistry, ;2023, 42(1): 100025. doi: 10.1016/j.cjsc.2023.100025 shu

AIO3∙H6TeO6 (A=NH4, Rb): Two Telluric Acid and Iodate Co-Crystalline Compounds with Second Harmonic Generation Response

The co-crystallization of telluric acid and iodate gives rise to two noncentrosymmetric crystals AIO3·H6TeO6 (A = Rb+, NH4+). They show different intensity of SHG responses due to the slight change of the orientation of [IO3] and [Te(OH)6] groups induced by different cations in A-site.
- Nonlinear optical,
- Co-crystalline,
- Isostructural,
- Local dipole moment,
- Second harmonic generation
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