Citation: Jingyuan Luo, Liping Wu, Jinxi Yan, Xintong Lv, Yuqi Luo, Wei Jiang, Zhiqiang Xiong, Anqi Ni, Chongbo Liu, Renchao Che. Radar-stealth and thermal-insulating MOF-derived cellulose-carbon aerogels for broadband electromagnetic wave absorption[J]. Chinese Chemical Letters, ;2025, 36(7): 111065. doi: 10.1016/j.cclet.2025.111065 shu

Radar-stealth and thermal-insulating MOF-derived cellulose-carbon aerogels for broadband electromagnetic wave absorption

Jingyuan Luo ^{a, 1} ,
Liping Wu ^{a, 1} ,
Jinxi Yan ^{a, 1} ,
Xintong Lv ^{a, 1} ,
Yuqi Luo ^a ,
Wei Jiang ^a ,
Zhiqiang Xiong ^a ,
Anqi Ni ^a ,
Chongbo Liu ^{a, *,} ,
Renchao Che ^{b, *,}

a.
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China
b.
Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Academy for Engineering & Technology, Fudan University, Shanghai 200438, China

cbliu2002@163.com

rcche@fudan.edu.cn

Received Date: 24 December 2024
Revised Date: 5 March 2025
Accepted Date: 10 March 2025
Available Online: 8 April 2025

Figures(4)

Considering the challenges posed by severe electromagnetic wave pollution and escalating international tensions, there is a critical need to develop advanced electromagnetic wave absorbing (EMWA) materials that integrate radar stealth and thermal insulation capabilities. In this study, we have synthesized three-dimensional (3D) porous composites comprising V₂O₃ nanoparticles embedded in Juncus effusus cellulose-derived carbon aerogels (VCA) using a self-templating method followed by high-temperature pyrolysis. The V₂O₃ nanoparticles possess a 3D V-V framework and a relatively narrow bandgap, facilitating the Mott transition for enhanced conductivity. Furthermore, their uniform dispersion on hollow carbon tubes of Juncus effusus promotes efficient electron transfer and creates numerous heterogeneous interfaces. Consequently, VCA-2 demonstrates outstanding EMWA performance, achieving a minimum reflection loss of −63.92 dB at a matching thickness of 2.0 mm and a maximum effective absorption bandwidth of 8.24 GHz at a thickness of 2.44 mm, covering nearly half of the tested frequency range. Additionally, the radar cross-section reduction reaches a peak value of 29.40 dB m², underscoring the excellent radar stealth capabilities of the material. In summary, VCA exhibits exceptional EMWA, radar stealth, and thermal insulation properties, highlighting its potential for multifunctional applications in EMWA material development.
- Vanadium-metal organic framework,
- Cellulose-derived carbon aerogels,
- Broadband electromagnetic wave absorption,
- Radar stealth,
- Thermal insulation
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1.
沈阳化工大学材料科学与工程学院沈阳 110142