Citation: Tianwen Chen, Chunqiang Cai, Li Chen, Yanlin Chen, Lichun Dong, Luxi Tan, Zitong Liu. Novel vinylene-bridged covalent organic framework based on diketopyrrolopyrrole with exceptional photothermal properties[J]. Chinese Chemical Letters, ;2025, 36(7): 111028. doi: 10.1016/j.cclet.2025.111028 shu

Novel vinylene-bridged covalent organic framework based on diketopyrrolopyrrole with exceptional photothermal properties

Tianwen Chen ^a ,
Chunqiang Cai ^a ,
Li Chen ^b ,
Yanlin Chen ^a ,
Lichun Dong ^a ,
Luxi Tan ^{a, *,} ,
Zitong Liu ^{c, *,}

a.
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
b.
School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, China
c.
State Key Laboratory of Applied Organic Chemistry (SKLAOC), College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

tanluxi@cqu.edu.cn

zitong_@iccas.ac.cn

Received Date: 4 December 2024
Revised Date: 26 February 2025
Accepted Date: 2 March 2025
Available Online: 3 March 2025

Figures(3)

Vinylene-bridged covalent organic frameworks (V-COFs), as fully conjugated polymer structures, offer promising prospects in optoelectronics. However, challenges such as poor bond reversibility and limited monomer availability persist. In this study, we introduce Ph-DPP-COF, synthesized from a diketopyrrolopyrrole (DPP) core with methyl groups via a Knoevenagel condensation reaction. The resulting material features an AA stacking mode, large nanopores, and broad light absorption across the ultraviolet to near-infrared spectrum. Notably, Ph-DPP-COF achieves a photothermal conversion efficiency of 53% under 660 nm laser irradiation. Its exceptional mechanical processability also offers considerable plasticity for practical applications. These findings suggest that Ph-DPP-COF not only provides a novel approach for developing photothermal conversion materials but also holds promise for future energy conversion and storage technologies.
- Covalent organic frameworks (COFs),
- Diketopyrrolopyrrole (DPP),
- Vinylene-bridged structures,
- Knoevenagel condensation,
- Photothermal conversion
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