Citation: Shilong Li, Ming Zhao, Yefei Xu, Zhanyi Liu, Mian Li, Qing Huang, Xiang Wu. Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating[J]. Chinese Chemical Letters, ;2025, 36(3): 110701. doi: 10.1016/j.cclet.2024.110701 shu

Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating

Shilong Li ^{a, 1} ,
Ming Zhao ^{a, 1} ,
Yefei Xu ^b ,
Zhanyi Liu ^b ,
Mian Li ^{b, *,} ,
Qing Huang ^b ,
Xiang Wu ^{a, *,}

a.
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
b.
Zhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

limian@nimte.ac.cn

wuxiang05@sut.edu.cn

Received Date: 14 October 2024
Revised Date: 26 November 2024
Accepted Date: 29 November 2024
Available Online: 30 November 2024

Figures(6)

Manganese dioxide (MnO₂) electrode material possesses the advantages of high energy density, structural diversity and high modification potential. This allows it become one of the important cathodes for aqueous zinc ion battery. However, the applications are limited by the poor electrical conductivity, narrow layer spacing and the ease of dissolution. Herein, we prepare MnO₂-PVP@0.03GO composites by the co-modification of polyvinylpyrrolidone (PVP) pre-insertion layer and graphene oxide (GO) self-assembly layer. The Zn//MnO₂-PVP@0.03GO cells deliver a discharge specific capacity of 442 mAh/g at a current density of 0.2 A/g. It also maintains 100% capacity for 1000 times cycling at 1 A/g. The assembled soft package batteries demonstrate superior flexibility and adaptability under different bending conditions.
- Aqueous zinc ion batteries,
- Cathode,
- MnO₂,
- Cycle stability,
- High capacity
1. [1]
  Y. Liu, X. Wu, Chin. Chem. Lett. 33 (2022) 1236-1244. doi: 10.1016/j.cclet.2021.08.081
2. [2]
  C. Li, X. Xie, S. Liang, J. Zhou et al., Energy Environ. Mater. 3 (2020) 146-159. doi: 10.1002/eem2.12067
3. [3]
  Y. Liu, Y. Liu, X. Wu, et al., J. Colloid Interface Sci. 628 (2022) 33-40. doi: 10.1016/j.jcis.2022.08.046
4. [4]
  Z. Pei, Nano Res. Energy 1 (2022) e9120023. doi: 10.26599/nre.2022.9120023
5. [5]
  X. Guo, C. Wang, W. Wang et al. Nano Res. Energy 1 (2022) e9120026. doi: 10.26599/nre.2022.9120026
6. [6]
  L. Chen, Q. An, L. Mai, Adv. Mater. Interface. 6 (2019) 1900387. doi: 10.1002/admi.201900387
7. [7]
  C. Su, X. Gao, K. Liu, et al., Nano Res. Energy 3 (2024) e9120094. doi: 10.26599/nre.2023.9120094
8. [8]
  K. Yao, S. Xu, Y. Yang, et al., Inf. Funct. Mater. 1 (2024) 242-263. doi: 10.1002/ifm2.22
9. [9]
  S. Liu, L. Kang, J. Kim, et al., Adv. Energy Mater. 10 (2020) 2000477. doi: 10.1002/aenm.202000477
10. [10]
  Y. Liu, X. Wu, J. Energy Chem. 87 (2023) 334-341. doi: 10.3390/atmos14020334
11. [11]
  C. Zhao, Y. Liu, S. Li, et al., Chin. Chem. Lett. (2024), doi:10.1016/j.cclet.2024.110185. doi: 10.1016/j.cclet.2024.110185
12. [12]
  V. Mathew, B. Sambandam, S. Kim, ACS Energy Lett. 5 (2020) 2376. doi: 10.1021/acsenergylett.0c00740
13. [13]
  X. Jia, C. Liu, Z.G. Neale, et al., Chem. Rev. 120 (2020) 7795-7866. doi: 10.1021/acs.chemrev.9b00628
14. [14]
  D. Chen, M. Lu, D. Cai et al., J. Energy Chem. 54 (2021) 712-726. doi: 10.1016/j.jechem.2020.06.016
15. [15]
  Y. Zuo, T. Meng, H. Tian, et al., ACS Nano 17 (2023) 5600-5608. doi: 10.1021/acsnano.2c11469
16. [16]
  B. Sambandam, V. Mathew, S. Kim, et al., Chem 8 (2022) 924-946. doi: 10.1016/j.chempr.2022.03.019
17. [17]
  T. Xiong, Z. Yu, H. Wu, et al., Adv. Energy Mater. 9 (2019) 1803815. doi: 10.1002/aenm.201803815
18. [18]
  Y. Li, D. Zhang, S. Huang, et al., Nano Energy 85 (2021) 105969. doi: 10.1016/j.nanoen.2021.105969
19. [19]
  J. Post, Proc. Natl. Acad. Sci. U. S. A. 96 (1999) 3447-3454. doi: 10.1073/pnas.96.7.3447
20. [20]
  D. Wang, L. Wang, G. Liang, et al., ACS Nano 13 (2019) 10643-10652. doi: 10.1021/acsnano.9b04916
21. [21]
  P. Simon, Y. Gogotsi, Nat. Mater. 20 (2021) 1597-1598. doi: 10.1038/s41563-021-01155-4
22. [22]
  N. Li, Z. Hou, S. Liang, et al., Chem. Eng. J. 452 (2023) 139408. doi: 10.1016/j.cej.2022.139408
23. [23]
  X. Xiao, L. Zhang, W. Xin, et al., Small 20 (2024) 2309271. doi: 10.1002/smll.202309271
24. [24]
  Y. Fu, Q. Wei, G. Zhang, et al., Adv. Energy Mater. 8 (2018) 1801445. doi: 10.1002/aenm.201801445
25. [25]
  X. Li, Q. Zhou, Z. Yang, et al., Energy Environ. Mater. 6 (2023) e12378. doi: 10.1002/eem2.12378
26. [26]
  X. Chen, L. Wang, H. Li, et al., J. Energy Chem. 38 (2019) 20-25. doi: 10.1016/j.jechem.2018.12.023
27. [27]
  S. Deng, Z. Tie, F. Yue, et al., Angew. Chem. Int. Ed. 61 (2022) e202115877. doi: 10.1002/anie.202115877
28. [28]
  I. Safo, C. Dosche, M. Özaslan, ChemPhysChem 20 (2019) 3010-3023. doi: 10.1002/cphc.201900653
29. [29]
  X. Liao, C. Pan, Y. Pan, et al., J. Alloys Compd. 888 (2021) 161619. doi: 10.1016/j.jallcom.2021.161619
30. [30]
  Y. Liu, P. Zhang, J. Phys. Chem. C 121 (2017) 23488-23497. doi: 10.1021/acs.jpcc.7b07931
31. [31]
  X. Li, Q. Zhou, Z. Yang, et al., Energy Environ. Mater. 6 (2023) e12378. doi: 10.1002/eem2.12378
32. [32]
  N. Li, Z. Hou, S. Liang, Y. Cao, et al., Chem. Eng. J. 452 (2023) 139408. doi: 10.1016/j.cej.2022.139408
33. [33]
  J. Zhang, W. Li, J. Wang, et al., Angew. Chem. Int. Ed. 62 (2023) e202215654. doi: 10.1002/anie.202215654
34. [34]
  Q. Wang, Y. Yang, Mater. Sci. 10 (2020) 819-823.
35. [35]
  Y. Liu, X. Wu, Nano Energy 127 (2024) 109809. doi: 10.1016/j.nanoen.2024.109809
36. [36]
  M. Zhao, S. Li, X. Wu, Adv. Mater. Technol. 9 (2024) 2400125. doi: 10.1002/admt.202400125
37. [37]
  J. Huang, Z. Wang, M. Hou, et al., Nat. commun. 9 (2018) 2906. doi: 10.1038/s41467-018-04949-4
38. [38]
  M. Zhao, S. Li, X. Wu, et al., iScience 27 (2024) 110926. doi: 10.1016/j.isci.2024.110926
39. [39]
  Z. Zhang, B. Xi, X. Wang, et al., Adv. Funct. Mater. 31 (2021) 2103070. doi: 10.1002/adfm.202103070
40. [40]
  T. Xiong, Z. Yu, H. Wu, et al., Adv. Energy Mater. 9 (2019) 1803815. doi: 10.1002/aenm.201803815
41. [41]
  M. Zhao, S. Li, A. Umar, et al., Mater. Today Chem. 33 (2023) 101686. doi: 10.1016/j.mtchem.2023.101686
42. [42]
  Y. Zhao, P. Zhang, J. Liang, et al., Energy Storage Mater. 47 (2022) 424-433. doi: 10.3390/land11030424
43. [43]
  Q. Xie, G. Cheng, T. Xue, et al., Mater. Today Energy 24 (2022) 100934. doi: 10.1016/j.mtener.2021.100934
44. [44]
  N. Li, Z. Hou, S. Liang, et al., Chem. Eng. J. 452 (2023) 139408. doi: 10.1016/j.cej.2022.139408
45. [45]
  H. Tang, W. Chen, N. Li, et al., Energy Storage Mater. 48 (2022) 335-343. doi: 10.1016/j.ensm.2022.03.042
46. [46]
  M. Alfaruqi, S. Islam, V. Mathew, et al., Appl. Surf. Sci. 404 (2017) 435-442. doi: 10.1016/j.apsusc.2017.02.009
47. [47]
  A. Zhang, R. Zhao, Y. Wang, et al., Angew. Chem. Int. Ed. 62 (2023) e202313163. doi: 10.1002/anie.202313163
48. [48]
  T. Cetinkaya, M. Tokur, S. Ozcan, et al., Mater. Today: Proc. 2 (2015) 4223-4228. doi: 10.1016/j.matpr.2015.09.007
49. [49]
  X. Huang, K. Shi, J. Yang, et al. J. Power Sources 356 (2017) 72-79. doi: 10.1016/j.jpowsour.2017.04.065
50. [50]
  J. Heo, S. Chong, S. Kim, et al., Batt. Supercap. 4 (2021) 1881-1888. doi: 10.1002/batt.202100181
51. [51]
  S. Li, M. Zhao, D. Zhang, et al., Cryst. Growth Des. 23 (2023) 8156-8162. doi: 10.1021/acs.cgd.3c00864
1. [1]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
2. [2]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
3. [3]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
4. [4]
  Zhuangzhuang Zhang , Yaru Qiao , Jun Zhao , Dai-Huo Liu , Mengmin Jia , Hongwei Tang , Liang Wang , Dongmei Dai , Bao Li . Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode. Chinese Chemical Letters, 2025, 36(3): 109907-. doi: 10.1016/j.cclet.2024.109907
5. [5]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
6. [6]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
7. [7]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
8. [8]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
9. [9]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
10. [10]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
11. [11]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
12. [12]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
13. [13]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
14. [14]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
15. [15]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
16. [16]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
17. [17]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
18. [18]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
19. [19]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
20. [20]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(99)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Performance optimization of aqueous Zn/MnO2 batteries through the synergistic effect of PVP intercalation and GO coating

Metrics

通讯作者: 陈斌, bchen63@163.com

Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating