Citation: Yunxia Liu, Guandong Wu, Lin Li, Yiming Niu, Bingsen Zhang, Botao Qiao, Junhu Wang. Construction of sintering-resistant gold catalysts via ascorbic-acid inducing strong metal-support interactions[J]. Chinese Chemical Letters, ;2025, 36(4): 110608. doi: 10.1016/j.cclet.2024.110608 shu

Construction of sintering-resistant gold catalysts via ascorbic-acid inducing strong metal-support interactions

Yunxia Liu ^{a, b, c} ,
Guandong Wu ^{a, b} ,
Lin Li ^a ,
Yiming Niu ^d ,
Bingsen Zhang ^d ,
Botao Qiao ^{a, *,} ,
Junhu Wang ^{a, b, *,}

a.
CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
b.
Mössbauer Effect Data Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

bqiao@dicp.ac.cn

wangjh@dicp.ac.cn

Received Date: 12 June 2024
Revised Date: 14 October 2024
Accepted Date: 3 November 2024
Available Online: 4 November 2024

Figures(6)

Maintaining high metal dispersion of supported metal catalysts to achieve superior reactivity under harsh conditions poses one of the main challenges for their practical applications. Constructing and regulating the strong metal-support interactions (SMSI) by diverse methodologies has emerged as one of the promising approaches to fabricating robust supported metal catalysts. In this study, we report an L-ascorbic acid (AA)-inducing strategy to generate SMSI on a titania-supported gold (Au) catalyst after high-temperature treatment in an inert atmosphere (600 ℃, N₂). The AA-induced SMSI can efficiently stabilize Au nanoparticles (NPs) and preserve their catalytic performance. The detailed study reveals that the key to realizing this SMSI is the generation of oxygen vacancies within the TiO₂ support induced by the adsorbed AA, which drives the formation of the TiO_x permeable layer onto the Au NPs. The strategy could be extended to TiO₂-supported Au catalysts with different crystal phases and platinum group metals, such as Pt, Pd, and Rh. This work offers a promising novel route to design stable and efficient supported noble metal catalysts by constructing SMSI using simple reducing organic adsorbent.
- Supported metal catalyst,
- Adsorbate,
- L-Ascorbic acid,
- Oxygen vacancy,
- Strong metal-support interaction
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