Citation: Hao-Cong Li, Ming Zhang, Qiyan Lv, Kai Sun, Xiao-Lan Chen, Lingbo Qu, Bing Yu. Homogeneous catalysis and heterogeneous separation: Ionic liquids as recyclable photocatalysts for hydroacylation of olefins[J]. Chinese Chemical Letters, ;2025, 36(2): 110579. doi: 10.1016/j.cclet.2024.110579 shu

Homogeneous catalysis and heterogeneous separation: Ionic liquids as recyclable photocatalysts for hydroacylation of olefins

College of Chemistry, School of Life Sciences, Zhengzhou University, Zhengzhou 450001, China

qiyanlv@zzu.edu.cn

chenxl@zzu.edu.cn

bingyu@zzu.edu.cn

Received Date: 3 August 2024
Revised Date: 15 October 2024
Accepted Date: 23 October 2024
Available Online: 24 October 2024

Figures(7)

The photoinduced ligand-to-metal charge transfer (LMCT) process has been extensively investigated, however, the recovery of photocatalysts has remained a persistent challenge in the field. In light of this issue, a novel approach involving the development of iron-based ionic liquids as photocatalysts has been pursued for the first time, with the goal of simultaneously facilitating the LMCT process and addressing the issue of photocatalyst recovery. Remarkably, the iron-based ionic liquid 1-butyl-3-methylimidazolium tetrachloroferrate (C₄mim-FeCl₄) demonstrates exceptional recyclability and stability for the photocatalytic hydroacylation of olefins. This study will pave the way for new approaches to photocatalytic organic synthesis using ionic liquids as recyclable photocatalysts.
- LMCT,
- Ionic liquids,
- Homogeneous catalysis,
- Heterogeneous separation,
- Recyclable photocatalysts
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