Citation: Junyi Yu, Yin Cheng, Anhong Cai, Xianfeng Huang, Qingrui Zhang. Synthetic Cu(Ⅲ) from copper plating wastewater for onsite decomplexation of Cu(Ⅱ)- and Ni(Ⅱ)-organic complexes[J]. Chinese Chemical Letters, ;2025, 36(2): 110549. doi: 10.1016/j.cclet.2024.110549 shu

Synthetic Cu(Ⅲ) from copper plating wastewater for onsite decomplexation of Cu(Ⅱ)- and Ni(Ⅱ)-organic complexes

Junyi Yu ^a ,
Yin Cheng ^a ,
Anhong Cai ^a ,
Xianfeng Huang ^{a, *,} ,
Qingrui Zhang ^{b, *,}

a.
National and Local Joint Engineering Research Center for Ecological Treatment Technology of Urban Water Pollution, College of Life and Environmental Science, Wenzhou University, Wenzhou 325035, China
b.
State Key Laboratory of Metastable Materials Science and Technology, Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, China

xianfeng_huang@wzu.edu.cn

zhangqr@ysu.edu.cn

Received Date: 8 January 2024
Revised Date: 11 October 2024
Accepted Date: 13 October 2024
Available Online: 14 October 2024

Figures(6)

Herein, the Cu(Ⅲ) synthesized from copper plating effluent was developed for the first time to evaluate the onsite degradation performance of heavy metal complexes in the wastewater, thus achieving the purpose of "treating waste with waste". The results indicated that synthetic Cu(Ⅲ) presented the excellent decomplexation performance for Cu(Ⅱ)/Ni(Ⅱ)-organic complexes. The removal efficiency of Cu(Ⅱ)/Ni(Ⅱ)-EDTA significantly increased with increasing Cu(Ⅲ) dosage, and the degradation of Cu(Ⅱ)/Ni(Ⅱ)-EDTA by synthetic Cu(Ⅲ) system displayed highly pH-dependent reactivity. The radical quencher experiments confirmed that Cu(Ⅲ) direct oxidation were mainly involved in the degradation of Cu(Ⅱ)-EDTA. Additionally, the continuous decarboxylation process was proven to be the main degradation pathway of Cu(Ⅱ)-EDTA in Cu(Ⅲ) system. The coexisting substances (SO₄²⁻, Cl⁻ and fulvic acids) showed little impacts at low level for the removal of Cu(Ⅱ)/Ni(Ⅱ)-EDTA, while retarded the degradation of Cu(Ⅱ)-EDTA slightly at high level, which features high selective oxidation. Encouragingly, it was also effective to remove Cu(Ⅱ)/Ni(Ⅱ)-EDTA from in treating actual Cu/Ni-containing wastewater through synthetic Cu(Ⅲ) treatment.
- Copper plating wastewater,
- Cu(Ⅲ),
- Decomplexation,
- Treating waste with waste,
- Selectivity
1. [1]
  D. Yuan, C. Zhang, S. Tang, et al., Chin. Chem. Lett. 32 (2021) 3387–3392.
2. [2]
  Y. Ye, P. Yang, Y. Deng, et al., Chin. Chem. Lett. 33 (2022) 3127–3132.
3. [3]
  Z. Xu, Q. Zhang, X.C. Li, X.F. Huang, Chem. Eng. J. 429 (2022) 131688.
4. [4]
  L. Song, S. Jing, Y. Qiu, F. Liu, A. Li, Chin. Chem. Lett. 34 (2023) 107180.
5. [5]
  S. Wang, M.R. Razanajatovo, X. Du, et al., Chin. Chem. Lett. 35 (2024) 109140.
6. [6]
  L. Zhang, B. Wu, G. Zhang, Y. Gan, S. Zhang, Chem. Eng. J. 358 (2019) 1218–1226.
7. [7]
  J. Du, B. Zhang, J. Li, B. Lai, Chin. Chem. Lett. 31 (2020) 2575–2582.
8. [8]
  H. Tian, X. Wang, R. Pan, et al., Environ. Sci. Pollut. Res. 30 (2023) 62733–62743. doi: 10.1007/s11356-023-26594-1
9. [9]
  J. Zhao, X. Hu, L. Kong, X. Peng, J. Hazard. Mater. 465 (2024) 133131.
10. [10]
  X. Huang, X. Wang, D.X. Guan, et al., Environ. Sci. Pollut. Res. 26 (2019) 8516–8524. doi: 10.1007/s11356-018-04091-0
11. [11]
  C. Chen, A. Chen, X. Huang, et al., J. Clean. Prod. 298 (2021) 126837.
12. [12]
  B. Thalmann, U. von Gunten, R. Kaegi, Water Res. 134 (2018) 170–180.
13. [13]
  L. Wu, S. Garg, J. Xie, et al., Environ. Sci. Technol. 57 (2023) 12476–12488. doi: 10.1021/acs.est.3c02550
14. [14]
  C. Chen, P. Liu, Y. Li, et al., Water Res. 218 (2022) 118502.
15. [15]
  J. Du, T.D. Waite, P.M. Biesheuvel, W. Tang, J. Hazard. Mater. 442 (2023) 130023.
16. [16]
  Y. Liu, J. Li, B. Zhou, et al., Environ. Chem. Lett. 7 (2009) 363–368. doi: 10.1007/s10311-008-0180-z
17. [17]
  Z. Xu, C. Shan, B. Xie, Y. Liu, B. Pan, Appl. Catal. B 200 (2017) 439–447.
18. [18]
  S. Lan, Y. Xiong, S. Tian, J. Feng, T. Xie, Appl. Catal. B 183 (2016) 371–376.
19. [19]
  Z. Wang, J. Li, W. Song, X. Zhang, J. Song, Water Sci. Technol. 79 (2019) 589–596. doi: 10.2166/wcc.2018.167
20. [20]
  C. Durante, A.A. Isse, G. Sandona, A. Gennaro, Chemosphere 78 (2010) 620–625.
21. [21]
  Z. Yang, J. Qian, C. Shan, et al., Environ. Sci. Technol. 55 (2021) 14494–14514. doi: 10.1021/acs.est.1c05862
22. [22]
  M. Li, S. You, X. Duan, Y. Liu, Appl. Catal. B 312 (2022) 121419.
23. [23]
  J. Li, A.N. Pham, R. Dai, Z. Wang, T.D. Waite, J. Hazard. Mater. 392 (2020) 122261.
24. [24]
  F.E.K. Okaikue-Woodi, J.R. Ray, J. Mater. Chem. A 11 (2023) 13552–13563. doi: 10.1039/d3ta01950k
25. [25]
  S. Li, R. Zheng, Y. Zhou, et al., ACS ES&T Water 3 (2023) 488–499.
26. [26]
  Y. Wang, Y. Wu, Y. Yu, et al., Water Res. 186 (2020) 116326.
27. [27]
  S. Sun, C. Shan, Z. Yang, S. Wang, B. Pan, Environ. Sci. Technol. 56 (2021) 634–641.
28. [28]
  C. Li, V. Goetz, S. Chiron, J. Environ. Chem. Eng. 9 (2021) 105145.
29. [29]
  Y. Feng, W. Qing, L. Kong, et al., Water Res. 149 (2019) 1–8.
30. [30]
  J. Chen, X. Zhou, P. Sun, Y. Zhang, C.H. Huang, Environ. Sci. Technol. 53 (2019) 11774–11782. doi: 10.1021/acs.est.9b03873
31. [31]
  K. McCann, D.M. Brigham, S. Morrison, J.C. Braley, Inorg. Chem. 55 (2016) 11971–11978. doi: 10.1021/acs.inorgchem.6b02120
32. [32]
  J.S.D. Jeremias, J.Y. Lin, M.L.P. Dalida, M.C. Lu, J. Environ. Chem. Eng. 11 (2023) 109336.
33. [33]
  C. Ling, Y. Zhao, Z. Ren, et al., Chin. Chem. Lett. 30 (2019) 2196–2200.
34. [34]
  J. Yu, W. Deng, X. Huang, et al., J. Hazard. Mater. 465 (2024) 133521.
35. [35]
  M.C. Collivignarelli, A. Abbà, M. Bestetti, B.M. Crotti, M.C. Miino, Water Air Soil Pollut. 230 (2019) 101.
36. [36]
  D. Chen, C. Zhang, H. Rong, M. Zhao, S. Gou, Sep. Purif. Technol. 234 (2020) 116043.
37. [37]
  G.V. Buxton, Q.G. Mulazzani, A.B. Ross, J. Phys. Chem. Ref. Data 24 (1995) 1055–1349. doi: 10.1063/1.555966
38. [38]
  Z. Wang, Q. Liu, F. Yang, et al., Environ. Int. 132 (2019) 105128.
39. [39]
  X. Huang, Y. Wang, X. Li, et al., Environ. Sci. Technol. 53 (2019) 2036–2044. doi: 10.1021/acs.est.8b05346
40. [40]
  Y. Deng, A.D. Handoko, Y. Du, S. Xi, B.S. Yeo, ACS Catal. 6 (2016) 2473–2481. doi: 10.1021/acscatal.6b00205
41. [41]
  Q. Zhao, X. Zhang, D. Huang, et al., Chemosphere 284 (2021) 131329.
42. [42]
  D.G. Brown, U. Weser, Inorg. Chem. 19 (1980) 264–266. doi: 10.1021/ic50203a055
43. [43]
  L. Wang, H. Xu, N. Jiang, et al., Environ. Sci. Technol. 54 (2020) 4686–4694. doi: 10.1021/acs.est.0c00284
44. [44]
  N. Li, T. Liu, S. Xiao, et al., J. Hazard. Mater. 445 (2023) 130536.
45. [45]
  T. Wang, H. Zhang, A. Cai, et al., J. Environ. Manag. 370 (2024) 122798.
46. [46]
  M. Deborde, U. Von Gunten, Water Res. 42 (2008) 13–51.
47. [47]
  Y. Liu, Y. Yang, A. Li, et al., Appl. Catal. B 345 (2024) 123717.
48. [48]
  Z. Guan, Y. Guo, Z. Huang, et al., Chem. Eng. J. 428 (2022) 131250.
1. [1]
  Caixia Zhu , Qing Hong , Kaiyuan Wang , Yanfei Shen , Songqin Liu , Yuanjian Zhang . Single nanozyme-based colorimetric biosensor for dopamine with enhanced selectivity via reactivity of oxidation intermediates. Chinese Chemical Letters, 2024, 35(10): 109560-. doi: 10.1016/j.cclet.2024.109560
2. [2]
  Congyan Liu , Xueyao Zhou , Fei Ye , Bin Jiang , Bo Liu . Confined electric field in nano-sized channels of ionic porous framework towards unique adsorption selectivity. Chinese Chemical Letters, 2025, 36(2): 109969-. doi: 10.1016/j.cclet.2024.109969
3. [3]
  Zimo Yang , Yan Tong , Yongbo Liu , Qianlong Liu , Zhihao Ni , Yuna He , Yu Rao . Developing selective PI3K degraders to modulate both kinase and non-kinase functions. Chinese Chemical Letters, 2024, 35(11): 109577-. doi: 10.1016/j.cclet.2024.109577
4. [4]
  Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
5. [5]
  Weidan Meng , Yanbo Zhou , Yi Zhou . Green innovation unleashed: Harnessing tungsten-based nanomaterials for catalyzing solar-driven carbon dioxide conversion. Chinese Chemical Letters, 2025, 36(2): 109961-. doi: 10.1016/j.cclet.2024.109961
6. [6]
  Yun Wei , Lei Zhou , Wenbin Hu , Liming Yang , Guang Yang , Chaoqiang Wang , Hui Shi , Fei Han , Yufa Feng , Xuan Ding , Penghui Shao , Xubiao Luo . Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries: Process analysis and evaluation. Chinese Chemical Letters, 2024, 35(7): 109172-. doi: 10.1016/j.cclet.2023.109172
7. [7]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
8. [8]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
9. [9]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
10. [10]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
11. [11]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
12. [12]
  Shili Wang , Mamitiana Roger Razanajatovo , Xuedong Du , Shunli Wan , Xin He , Qiuming Peng , Qingrui Zhang . Recent advances on decomplexation mechanisms of heavy metal complexes in persulfate-based advanced oxidation processes. Chinese Chemical Letters, 2024, 35(6): 109140-. doi: 10.1016/j.cclet.2023.109140
13. [13]
  Qijun Tang , Wenguang Tu , Yong Zhou , Zhigang Zou . High efficiency and selectivity catalyst for photocatalytic oxidative coupling of methane. Chinese Journal of Structural Chemistry, 2023, 42(12): 100170-100170. doi: 10.1016/j.cjsc.2023.100170
14. [14]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
15. [15]
  Shiqi Xu , Zi Ye , Shuang Shang , Fengge Wang , Huan Zhang , Lianguo Chen , Hao Lin , Chen Chen , Fang Hua , Chong-Jing Zhang . Pairs of thiol-substituted 1,2,4-triazole-based isomeric covalent inhibitors with tunable reactivity and selectivity. Chinese Chemical Letters, 2024, 35(7): 109034-. doi: 10.1016/j.cclet.2023.109034
16. [16]
  Shaoming Dong , Yiming Niu , Yinghui Pu , Yongzhao Wang , Bingsen Zhang . Subsurface carbon modification of Ni-Ga for improved selectivity in acetylene hydrogenation reaction. Chinese Chemical Letters, 2024, 35(12): 109525-. doi: 10.1016/j.cclet.2024.109525
17. [17]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
18. [18]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
19. [19]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
20. [20]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(167)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142