Citation: Jianning Zhang, Yihuai Zhang, Guoxin Ma, Jingchen Zhao, Tao Zhang, Jian Liu. Enhancing hydrothermal stability in Cu/SSZ-13 catalyst for diesel SCR applications through a novel core-shell structure[J]. Chinese Chemical Letters, ;2025, 36(7): 110516. doi: 10.1016/j.cclet.2024.110516 shu

Enhancing hydrothermal stability in Cu/SSZ-13 catalyst for diesel SCR applications through a novel core-shell structure

Jianning Zhang ^{a, b} ,
Yihuai Zhang ^b ,
Guoxin Ma ^b ,
Jingchen Zhao ^{a, b} ,
Tao Zhang ^{b, *,} ,
Jian Liu ^{a, c, *,}

a.
College of Science, China University of Petroleum, Beijing 102249, China
b.
School of Chemistry and Life Resources, Renmin University of China, Beijing 100872, China
c.
Laboratory of Heavy Oil Processing at Karamay, China University of Petroleum-Beijing at Karamay, Karamay 834000, China

zhangt@ruc.edu.cn

Liujian@cup.edu.cn

Received Date: 23 April 2024
Revised Date: 9 August 2024
Accepted Date: 28 September 2024
Available Online: 30 September 2024

Figures(5)

This study introduces a novel core-shell structured composite, Cu/SSZ-13@CeO₂, designed to boost the catalyst’s resistance to hydrothermal conditions. Characterization results reveal that encapsulating Cu/SSZ-13 with a ceria (CeO₂) shell markedly enhances hydrothermal stability by maintaining the functionality of [Cu(OH)]⁺ active sites and averting their deactivation. Furthermore, the CeO₂ shell substantially prevents the loss of crucial Lewis and Brønsted acid sites, essential for effective SCR performance. A significant finding is the formation of a "Ce−O−Al" bond between the CeO₂ shell and the Cu/SSZ-13 core, which plays a crucial role in reinforcing the structural stability of the zeolite framework. These insights contribute significantly to the development of robust anti-hydrothermal aging catalysts for mobile SCR applications, heralding the advancement of more efficient SCR catalyst technologies.
- Diesel emission,
- NO_x,
- Hydrothermal aging,
- Cu/SSZ-13,
- Core-shell catalysts
1. [1]
  L. Han, S. Cai, M. Gao, et al., Chem. Rev. 119 (2019) 10916–10976. doi: 10.1021/acs.chemrev.9b00202
2. [2]
  M.V. Twigg, Appl. Catal. B 70 (2007) 2–15. doi: 10.1016/j.apcatb.2006.02.029
3. [3]
  R. Zhang, N. Liu, Z. Lei, et al., Chem. Rev. 116 (2016) 3658–3721. doi: 10.1021/acs.chemrev.5b00474
4. [4]
  L. Ma, Y. Cheng, G. Cavataio, et al., Appl. Catal. B 156–157 (2014) 428–437. doi: 10.1016/j.apcatb.2014.03.048
5. [5]
  Y.J. Kim, J.K. Lee, K.M. Min, et al., J. Catal. 311 (2014) 447–457. doi: 10.1016/j.jcat.2013.12.012
6. [6]
  M. Jabłońska, RSC Adv. 12 (2022) 25240–25261. doi: 10.1039/d2ra04301g
7. [7]
  K.A. Lomachenko, E. Borfecchia, C. Negri, et al., J. Am. Chem. Soc. 138 (2016) 12025–12028. doi: 10.1021/jacs.6b06809
8. [8]
  F. Gao, D. Mei, Y. Wang, et al., J. Am. Chem. Soc. 139 (2017) 4935–4942. doi: 10.1021/jacs.7b01128
9. [9]
  D. Wang, Y. Jangjou, Y. Liu, et al., Appl. Catal. B 165 (2015) 438–445. doi: 10.1016/j.apcatb.2014.10.020
10. [10]
  Y. Zhang, H. Zhu, T. Zhang, et al., Environ. Sci. Technol. 56 (2022) 1917–1926. doi: 10.1021/acs.est.1c06068
11. [11]
  T. Xu, G. Li, X. Zhu, et al., Fuel 353 (2023) 129292. doi: 10.1016/j.fuel.2023.129292
12. [12]
  S.J. Schmieg, S.H. Oh, C.H. Kim, et al., Catal. Today 184 (2012) 252–261. doi: 10.1016/j.cattod.2011.10.034
13. [13]
  L. Wu, B. Peng, Q. Li, et al., Environ. Sci. Pollut. R. 26 (2019) 19665–19675. doi: 10.1007/s11356-019-05161-7
14. [14]
  A. Mitra, M.K. Mishra, J. Saha, Micropor. Mesopor. Mat. 203 (2015) 151–162. doi: 10.1016/j.micromeso.2014.10.014
15. [15]
  T. Zhang, F. Qiu, J. Li, Appl. Catal. B 195 (2016) 48–58. doi: 10.1016/j.apcatb.2016.04.058
16. [16]
  P.K. Dutta, D.C. Shieh, M. Puri, Zeolites 8 (1988) 306–309. doi: 10.1016/S0144-2449(88)80127-1
17. [17]
  J. Zhang, Y. Chu, X. Liu, et al., Chin. J. Catal. 40 (2019) 1854–1859. doi: 10.1016/S1872-2067(19)63287-0
18. [18]
  P.K. Dutta, M. Puri, J. Phys. Chem. A 91 (1987) 4329–4333. doi: 10.1021/j100300a025
19. [19]
  Z. Wu, M. Li, J. Howe, et al., Langmuir 26 (2010) 16595–16606. doi: 10.1021/la101723w
20. [20]
  K.U. Gore, A. Abraham, S.G. Hegde, et al., J. Phys. Chem. B 106 (2002) 6115–6120. doi: 10.1021/jp0143241
21. [21]
  J. Song, Y. Wang, E.D. Walter, et al., ACS Catal. 7 (2017) 8214–8227. doi: 10.1021/acscatal.7b03020
22. [22]
  R.A. Beyerlein, C. Choi-Feng, J.B. Hall, et al., Top. Catal. 4 (1997) 27–42. doi: 10.1023/A:1019188105794
23. [23]
  J.H. Kwak, H. Zhu, J.H. Lee, et al., Chem. Commun. 48 (2012) 4758–4760. doi: 10.1039/c2cc31184d
24. [24]
  B. Mark, H.P. Jacqueline, A.S. Valerie, et al., Appl. Catal. 58 (1990) 147–153. doi: 10.1016/S0166-9834(00)82284-8
25. [25]
  T. Sutarat, K. Sirapassorn, J. Anchalee, et al., Catal. Commun. 169 (2022) 106468. doi: 10.1016/j.catcom.2022.106468
26. [26]
  H. Zhu, Z. Qin, W. Shan, et al., J. Catal. 225 (2004) 267–277. doi: 10.1016/j.jcat.2004.04.006
27. [27]
  W. Shan, H. Guo, C. Liu, et al., J. Rare Earth 30 (2012) 665–669. doi: 10.1016/S1002-0721(12)60109-4
28. [28]
  J.H. Kwak, T. Varga, C.H.F. Peden, et al., J. Catal. 314 (2014) 83–93. doi: 10.1016/j.jcat.2014.03.003
29. [29]
  J. Luo, D. Wang, A. Kumar, Catal. Today 267 (2016) 3–9. doi: 10.1016/j.cattod.2015.12.002
30. [30]
  A. Godiksen, F.N. Stappen, P.N.R. Vennestrøm, et al., J. Phys. Chem. C 118 (2014) 23126–23138. doi: 10.1021/jp5065616
31. [31]
  Y. Zhang, Y. Wu, Y. Peng, et al., J. Phys. Chem. C 124 (2020) 28061–28073. doi: 10.1021/acs.jpcc.0c07971
32. [32]
  J.P. Holgado, R. Alvarez, G. Munuera, Appl. Surf. Sci. 161 (2000) 301–315. doi: 10.1016/S0169-4332(99)00577-2
33. [33]
  A.R. González-Elipe, A. Fernández, J.P. Holgado, et al., J. Vac. Sci. Technol. A 11 (1993) 58–65. doi: 10.1116/1.578720
34. [34]
  M. Mazloum-Ardakani, F. Sabaghian, M. Yavari, et al., J. Alloys Compd. 819 (2020) 152949. doi: 10.1016/j.jallcom.2019.152949
35. [35]
  B.M. Reddy, A. Khan, P. Lakshmanan, et al., J. Phys. Chem. B 109 (2005) 3355–3363. doi: 10.1021/jp045193h
36. [36]
  M. Rashad, M. Rüsing, G. Berth, et al., J. Nanomater. 2013 (2013) 82. doi: 10.1155/2013/714853
37. [37]
  I. Lezcano-Gonzalez, U. Deka, B. Arstad, et al., Phys. Chem. Chem. Phys. 16 (2014) 1639–1650. doi: 10.1039/C3CP54132K
38. [38]
  C. Negri, E. Borfecchia, M. Cutini, et al., ChemCatChem 11 (2019) 3828–3838. doi: 10.1002/cctc.201900590
39. [39]
  G. Qi, R.T. Yang, R. Chang, Appl. Catal. B 51 (2004) 93–106. doi: 10.1016/j.apcatb.2004.01.023
40. [40]
  B. Liu, J. Xin, T. Zhang, et al., ACS Catal. 11 (2021) 7613–7636. doi: 10.1021/acscatal.1c00311
1. [1]
  Shanyuan Bi , Jin Zhang , Dengchao Peng , Danhong Cheng , Jianping Zhang , Lupeng Han , Dengsong Zhang . Improved N₂ selectivity for low-temperature NO_x reduction over etched ZSM-5 supported MnCe oxide catalysts. Chinese Chemical Letters, 2025, 36(5): 110295-. doi: 10.1016/j.cclet.2024.110295
2. [2]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
3. [3]
  Jinpeng Du , Junlin Chen , Yulong Shan , Tongliang Zhang , Yu Sun , Zhongqi Liu , Xiaoyan Shi , Wenpo Shan , Yunbo Yu , Hong He . Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts. Chinese Chemical Letters, 2025, 36(3): 110019-. doi: 10.1016/j.cclet.2024.110019
4. [4]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
5. [5]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
6. [6]
  Yaoyin Lou , Xiaoyang Jerry Huang , Kuang-Min Zhao , Mark J. Douthwaite , Tingting Fan , Fa Lu , Ouardia Akdim , Na Tian , Shigang Sun , Graham J. Hutchings . Stable core-shell Janus BiAg bimetallic catalyst for CO₂ electrolysis into formate. Chinese Chemical Letters, 2025, 36(3): 110300-. doi: 10.1016/j.cclet.2024.110300
7. [7]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
8. [8]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240
9. [9]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
10. [10]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
11. [11]
  Zihong Li , Jie Cheng , Ping Huang , Guoliang Wu , Weiying Lin . Activatable photoacoustic bioprobe for visual detection of aging in vivo. Chinese Chemical Letters, 2024, 35(4): 109153-. doi: 10.1016/j.cclet.2023.109153
12. [12]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
13. [13]
  Shengfei Dong , Ziyu Liu , Xiaoyi Yang . Hydrothermal liquefaction of biomass for jet fuel precursors: A review. Chinese Chemical Letters, 2024, 35(8): 109142-. doi: 10.1016/j.cclet.2023.109142
14. [14]
  Guo-Hong Gao , Run-Ze Zhao , Ya-Jun Wang , Xiao Ma , Yan Li , Jian Zhang , Ji-Sen Li . Core–shell heterostructure engineering of CoP nanowires coupled NiFe LDH nanosheets for highly efficient water/seawater oxidation. Chinese Chemical Letters, 2024, 35(8): 109181-. doi: 10.1016/j.cclet.2023.109181
15. [15]
  Rui Cheng , Xin Huang , Tingting Zhang , Jiazhuang Guo , Jian Yu , Su Chen . Solid superacid catalysts promote high-performance carbon dots with narrow-band fluorescence emission for luminescence solar concentrators. Chinese Chemical Letters, 2024, 35(8): 109278-. doi: 10.1016/j.cclet.2023.109278
16. [16]
  Gangsheng Li , Xiang Yuan , Fu Liu , Zhihua Liu , Xujie Wang , Yuanyuan Liu , Yanmin Chen , Tingting Wang , Yanan Yang , Peicheng Zhang . Three-step synthesis of flavanostilbenes with a 2-cyclohepten-1-one core by Cu-mediated [5 + 2] cycloaddition/decarboxylation cascade. Chinese Chemical Letters, 2025, 36(2): 109880-. doi: 10.1016/j.cclet.2024.109880
17. [17]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
18. [18]
  Jing-Jing Zhang , Lujun Lou , Rui Lv , Jiahui Chen , Yinlong Li , Guangwei Wu , Lingchao Cai , Steven H. Liang , Zhen Chen . Recent advances in photochemistry for positron emission tomography imaging. Chinese Chemical Letters, 2024, 35(8): 109342-. doi: 10.1016/j.cclet.2023.109342
19. [19]
  Bowen Xu , Jiahao Chen , Lulu Cui , Xinyue Li , Yuan Xue , Sheng Han . Terpolymers of alkyl methacrylate-trans anethole-1,2,3,6-tetrahydrophthalic anhydride copolymers: A low dosage and high-efficiency cold flow improver for diesel fuel. Chinese Chemical Letters, 2025, 36(5): 110196-. doi: 10.1016/j.cclet.2024.110196
20. [20]
  Yufei Liu , Liang Xiong , Bingyang Gao , Qingyun Shi , Ying Wang , Zhiya Han , Zhenhua Zhang , Zhaowei Ma , Limin Wang , Yong Cheng . MOF-derived Cu based materials as highly active catalysts for improving hydrogen storage performance of Mg-Ni-La-Y alloys. Chinese Chemical Letters, 2024, 35(12): 109932-. doi: 10.1016/j.cclet.2024.109932

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(4)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142